Zobrazeno 1 - 10
of 53
pro vyhledávání: '"Brian C. Manor"'
Autor:
Jacob M. Kirsh, Audra J. Woodside, Brian C. Manor, Patrick J. Carroll, Paul R. Rablen, Christopher R. Graves
Publikováno v:
Inorganics, Vol 6, Iss 2, p 50 (2018)
We report the synthesis of a gallium complex incorporating redox-active pyridyl nitroxide ligands. The (pyNO−)2GaCl complex was prepared in 85% yield via a salt metathesis route and was characterized by 1H and 13C NMR spectroscopies, X-ray diffract
Externí odkaz:
https://doaj.org/article/bc915da8763244bdaac1085080f34dbd
Autor:
Laura M. Thierer, Sam H. Brooks, Alexander B. Weberg, Peng Cui, Shaoguang Zhang, Michael R. Gau, Brian C. Manor, Patrick J. Carroll, Neil C. Tomson
Publikováno v:
Inorg Chem
A synthetic route has been developed for a series of 3d homobimetallic complexes of Mn, Fe, Co, Ni and Cu using three different pyridyldiimine (PDI) and pyridyldialdimine (PDAI) macrocyclic ligands with ring sizes of 18, 20 and 22 atoms. Crystallogra
Autor:
Liane M. Moreau, Ekaterina Lapsheva, Jorge I. Amaro-Estrada, Michael R. Gau, Patrick J. Carroll, Brian C. Manor, Yusen Qiao, Qiaomu Yang, Wayne W. Lukens, Dimosthenis Sokaras, Eric J. Schelter, Laurent Maron, Corwin H. Booth
Publikováno v:
Chemical science, vol 13, iss 6
Chemical Science
Chemical Science, 2022, 13 (6), pp.1759-1773. ⟨10.1039/d1sc06623d⟩
Chemical Science
Chemical Science, 2022, 13 (6), pp.1759-1773. ⟨10.1039/d1sc06623d⟩
This study presents the role of 5d orbitals in the bonding, and electronic and magnetic structure of Ce imido and oxo complexes synthesized with a tris(hydroxylaminato) [((2- t BuNO)C6H4CH2)3N]3- (TriNO x 3-) ligand framework, including the reported
Autor:
Patrick J. Carroll, Michael R. Gau, Grace B. Panetti, Brian C. Manor, Patrick J. Walsh, Eric J. Schelter
Publikováno v:
Chemical Science
The super electron donor (SED) ability of 2-azaallyl anions has recently been discovered and applied to diverse reactivity, including transition metal-free cross-coupling and dehydrogenative cross-coupling processes. Surprisingly, the redox propertie
Autor:
Robert F. Higgins, Brian C. Manor, Liane M. Moreau, Rulin Feng, Haolin Yin, Patrick J. Carroll, Corwin H. Booth, Eric J. Schelter, Yusen Qiao, Jochen Autschbach
Publikováno v:
Chemical Science
A series of cerium(iv) mixed-ligand guanidinate–amide complexes, {[(Me3Si)2NC(NiPr)2]xCeIV[N(SiMe3)2]3−x}+ (x = 0–3), was prepared by chemical oxidation of the corresponding cerium(iii) complexes, where x = 1 and 2 represent novel complexes. Th
Autor:
Thibault Cheisson, Bren E. Cole, Eric J. Schelter, Brian C. Manor, Robert F. Higgins, Patrick J. Carroll
Publikováno v:
Angewandte Chemie. 132:1867-1872
The separation of rare-earth ions from one another is challenging due to their chemical and physical similarities. Nearly all rare-earth separations rely upon small changes in ionic radii to direct speciation or reactivity. Herein, we show that the i
Autor:
Neil C. Tomson, Laura M. Thierer, Alexander B. Weberg, Michael R. Gau, Shaoguang Zhang, Patrick J. Carroll, Peng Cui, Qiuran Wang, Brian C. Manor
Publikováno v:
Inorganic Chemistry. 59:4200-4214
This report describes an isostructural series of dinuclear iron, cobalt, and nickel complexes bound by a redox-active macrocyclic ligand. The series spans five redox levels (34–38 e–/cluster core),...
Autor:
Robert F. Higgins, Brian C. Manor, Eiko Nakamaru-Ogiso, Thibault Cheisson, Eric J. Schelter, Bren E. Cole, Patrick J. Carroll
Publikováno v:
Inorganic Chemistry. 59:172-178
Separation of the rare-earth (RE) elements (Sc, Y, La-Lu) is challenging because of their similar chemical properties, but is necessary for their applications in renewable energy and electronic device technologies. The development of separation proce
Autor:
Audra J. Woodside, Thomas M. Herb, Christopher R. Graves, Paul R. Rablen, Patrick J. Carroll, Brian C. Manor, Mackinsey A. Smith
Publikováno v:
Organometallics. 38:1017-1020
An aluminum complex of a tripodal tris(nitroxide)-based ligand has been prepared and characterized. The complex has the ability to participate in metal–ligand cooperative catalysis, which has been exploited for the hydroboration of both aldehydes a
Publikováno v:
ACS Sustainable Chemistry & Engineering. 7:4993-5001
Phosphoryl ligands of the general formula O═PR3 (R = Me, OMe, Et, nBu, Ph, iPr, NMe2) were coordinated to [Nd(TriNOx)] (TriNOx3– = ([(2-tBuNO)C6H4CH2]3N)3–), and the resulting complexes were characterized. Solution equilibrium constants for eac