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of 32
pro vyhledávání: '"Briac Tobey"'
The controlled hydrolysis of TpBeCl {Tp = trispyrazolylborate [HB(C3N2H3)3]–} with H2O and D2O in the presence of N,N-diisopropylethylamine (DIPEA) yields the trimeric beryllium hydroxide scorpionate complexes [Be3(µ-OX)3(Tp)3] (X = H: 1, D: 2) qu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00688b6d148aad79ff6d16f57136792d
https://duepublico2.uni-due.de/servlets/MCRFileNodeServlet/duepublico_derivate_00073263/Accepted_Manuscript_Eur_J_Inorg_Chem_2016_2424.pdf
https://duepublico2.uni-due.de/servlets/MCRFileNodeServlet/duepublico_derivate_00073263/Accepted_Manuscript_Eur_J_Inorg_Chem_2016_2424.pdf
Autor:
Briac Tobey, Christoph Wölper, Stephan Schulz, Dieter Bläser, Benjamin Lyhs, Georg Jansen, Dominik Naglav, Beate Römer
Publikováno v:
Angewandte Chemie. 129:8680-8685
[Ph4P]2[Be(N3)4] (1) und [PNP]2[Be(N3)4] (2; PNP=Ph3PNPPh3) wurden durch Reaktion von Be(N3)2 mit [Ph4P]N3 und [PNP]N3 synthetisiert. Das Tetraazidoberyllat-Dianion [Be(N3)4]2− (1′) reprasentiert das erste strukturell charakterisierte homoleptisc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::87e9ceb2dd2275db3db3a3b93f6638a1
https://doi.org/10.1002/ange.201703147
https://doi.org/10.1002/ange.201703147
Autor:
Dominik Naglav-Hansen, Briac Tobey, Christoph Wölper, Kevin Dzialkowski, Stephan Schulz, Georg Jansen
We present the reaction of a tris(pyrazolyl) beryllium scorpionate (TpBe) complex with a weakly coordinating anion (WCA), which yields the heteroleptic complex TpBeOC(CF3)3 1 (TpBeOR F). The product 1 has been characterized by multinuclear NMR spectr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b718a268a4bc8f6d7e9cc395237f2a3f
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85083400116
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85083400116
Autor:
Dieter Bläser, Kevin Dzialkowski, Dominik Naglav, Briac Tobey, Stephan Schulz, Christoph Wölper, Georg Jansen
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 47(36)
Methanetrisamidines {HC[C(NR)NHR]3} (R = i-Pr 1a; Ph 1b) were reacted with different metal complexes. Reaction of 1a with NiCl2(H2O)6 occurred with protonation of 1a and formation of {[C(C(NHi-Pr)2)3]2+[NiCl4]2−} 2, whereas the reaction with CuCl g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a250d299bc4a71e2b181d2fc1c501bcd
https://pubmed.ncbi.nlm.nih.gov/29786735
https://pubmed.ncbi.nlm.nih.gov/29786735
Autor:
Stephan Schulz, Christoph Wölper, Beate Römer, Dominik Naglav, Benjamin Lyhs, Dieter Bläser, Georg Jansen, Briac Tobey
Publikováno v:
Angewandte Chemie (International ed. in English). 56(29)
[Ph4P]2[Be(N3)4] (1) and [PNP]2[Be(N3)4] (2; PNP=Ph3PNPPh3) were synthesized by reacting Be(N3)2 with [Ph4P]N3 and [PNP]N3. Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding si
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9388a0fbd9a4e28e157e0634b732694f
https://pubmed.ncbi.nlm.nih.gov/28556359
https://pubmed.ncbi.nlm.nih.gov/28556359
Autor:
Peter Barthen, Dieter Bläser, Hermann-Josef Frohn, Georg Jansen, Briac Tobey, Markus E. Hirschberg
Publikováno v:
Journal of Fluorine Chemistry. 163:28-33
The iodonium pseudohalide compounds, [(C6F5)2I][X] (X = SCN and CN) were synthesized by means of fluoride substitution in [(C6F5)2I][F] with the Lewis acidic reagents (CH3)3Si–NCS and (CH3)3Si–CN. The isolated iodonium pseudohalides are intrinsic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::595a2ba151f9d8b4f8947b2075117864
https://doi.org/10.1016/j.jfluchem.2014.04.006
https://doi.org/10.1016/j.jfluchem.2014.04.006
Publikováno v:
European Journal of Inorganic Chemistry. 2013:4146-4149
Solid “GaI” reacts with NaCp to give (η5-cyclopentadienyl)gallium (GaCp). Further reaction of a solution of GaCp with [Cr(CO)5(coe)] (coe = cyclooctene) or Co2(CO)8 leads to CpGa–Cr(CO)5 (1) or (thf)GaCp{Co(CO)4}2 (4), respectively, which show
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b6bd4a66cbde40a9bae4944f4cb49805
https://doi.org/10.1002/ejic.201300401
https://doi.org/10.1002/ejic.201300401
Publikováno v:
Zeitschrift fur Anorganische und Allgemeine Chemie, 639(2), 354-359. WILEY-V C H VERLAG GMBH
GeCpbig2 (1) [Cpbig = C5(CH2C6H4-iPr)5] was synthesized by a reaction of KCpbig either with a GeCl solution or GeCl2 and was obtained as colorless crystals. The molecular structure of 1 was determined by X-ray diffraction, showing that 1 features two
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::66439799e6f3433248ea3270c19070d4
https://doi.org/10.1002/zaac.201200242
https://doi.org/10.1002/zaac.201200242
The solid-state structures of half-sandwich beryllium complexes Cp*BeX (X = Cl (1), Br (2), I (3)) are described. All attempts to synthesize Cp*BeF (4) by reaction of 1–3 with several fluorinating reagents such as AgF2, XeF2, 4-FC6H4IF2, AgF, NaF,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e5fe64aee04bb67eeca2af4dcdec01e
https://duepublico2.uni-due.de/receive/duepublico_mods_00073458
https://duepublico2.uni-due.de/receive/duepublico_mods_00073458
Autor:
Briac Tobey, Stephan Schulz, Dominik Naglav, Christoph Wölper, Kevin Dzialkowski, Georg Jansen
Publikováno v:
Inorganics; Volume 5; Issue 2; Pages: 22
We present the synthesis of two silyl beryllium halides HypSiBeX∙(thf) (HypSi = Si(SiMe3)3, X = Cl 2a, I 4a) and the molecular structure of 2a as determined by single crystal X-ray diffraction. Compounds 2a and 4a were characterized via multi-nucle
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ac401a9192af0d8fc520771189118bdd
https://doi.org/10.3390/inorganics5020022
https://doi.org/10.3390/inorganics5020022