Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Brassard's diene"'
Publikováno v:
Molecules, Vol 25, Iss 2, p 394 (2020)
All four chiral pestalotin diastereomers were synthesized in a straightforward and divergent manner from common (R)-glycidol. Catalytic asymmetric Mukaiyama aldol reactions of readily-available bis(TMSO)diene (Chan’s diene) with (S)-2-benzyloxyhexa
Externí odkaz:
https://doaj.org/article/59301912c2bf449f873c58aeadfb5cef
Autor:
G. Gerstberger
Publikováno v:
Catalysis from A to Z.
Akademický článek
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Publikováno v:
Tetrahedron Letters. 51:3088-3091
The chiral N , N′ -dioxide–Yb(OTf) 3 complex-catalyzed enantioselective aza-Diels–Alder reaction of Brassard’s diene with aldimines has been developed, giving the corresponding α,β-unsaturated δ-lactam derivatives in moderate yields with g
Publikováno v:
Organic Letters. 10:1311-1314
An efficient catalytic asymmetric hetero-Diels-Alder reaction of Brassard's diene with aliphatic aldehydes was reported. The catalyst, which was generated from (R)-BINOL, Ti(i-PrO)4, and 4-picolyl chloride hydrochloride, promoted the reaction smoothl
Publikováno v:
Angewandte Chemie International Edition. 45:4796-4798
Autor:
Ralf Lock, Herbert Waldmann
Publikováno v:
Natural Product Letters. 2:49-56
Schiff's bases 3 derived from tryptamine react with Brassard's diene 4 in the presence of EtAlCl2 to give functionalized 1,2,5,6-tetrahydropyridines which are subsequently transformed to indolo[2,3-a]quinolizines 8–10 by the Bischler-Napieralski re
Publikováno v:
ChemInform. 41
The catalyst generated promotes the asymmetric reaction of the diene (I) with aromatic and conjugated aldehydes to give functionalized esters of type (III) with excellent enantioselectivity.
Publikováno v:
ChemInform. 41
The reaction is optimized with respect to the catalyst and used for the synthesis of α,β-unsaturated δ-lactams as precursors of highly functionalized piperidines.
Publikováno v:
ChemInform. 23