Zobrazeno 1 - 10
of 44
pro vyhledávání: '"Bradley W. Smucker"'
Publikováno v:
IUCrData, Vol 9, Iss 3, p x240191 (2024)
The structure of the title compound, [RuCl2(C7H10N2)2(C2H6OS)2], has monoclinic (P21/n) symmetry. The Ru—N distances of the coordination compound are influenced by the trans chloride or dimethylsulfoxide-κS ligands. The molecular structure exhibit
Externí odkaz:
https://doaj.org/article/e3f966960d64473d9ce21863f3a71d70
Autor:
Eric W. Reinheimer, Rebecca A. Tobias, Elisabeth R. Bassel, Nicholas A. Cantu, Bradley W. Smucker
Publikováno v:
IUCrData, Vol 8, Iss 2, p x230155 (2023)
The structure of the title complex, [RuCl2(C6H6NO)4], exhibits point group symmetry \overline{4}. The structure exhibits disorder around a \overline{4} axis. The 4-methoxypyridine ligands have a propeller-like arrangement around the RuII atom at 52.0
Externí odkaz:
https://doaj.org/article/d90f4f7e356f4184b2d29b9b2097b674
Publikováno v:
IUCrData, Vol 7, Iss 2, p x220101 (2022)
In the structure of the title solvated complex, [Pt(C8H4N2S2)2(C5H6N2)2]·C2H6OS or trans-[Pt(4-ap)2(qdt)2]·dmso (4-ap = 4-aminopyridyl, C5H6N2; qdt = quinoxaline-2,3-dithiolate, C8H4N2S2; dmso = dimethyl sulfoxide, C2H6OS) the centrosymmetric compl
Externí odkaz:
https://doaj.org/article/036a5c13cc16469791a3063f316e2ead
Publikováno v:
IUCrData, Vol 5, Iss 7, p x200980 (2020)
The title compound, [Pt(C4N2S2)2(NH3)2], represents an octahedral platinum(IV) complex with two trans-ammine and two mnt (mnt = 1,2-dicyanoethene-1,2-dithiolato) ligands. The Pt—N and Pt—S distances are consistent with those in other platinum(IV)
Externí odkaz:
https://doaj.org/article/ffde7d1e646944f9979807afde16a718
Publikováno v:
IUCrData, Vol 5, Iss 7, p x200998 (2020)
The title compound, {[CuI(bpe)]·0.25(bpe)}n, was synthesized similarly to (CuI)2(bpe) [Neal et al. (2019). IUCrData, 4, x190122] with red crystals grown from acetonitrile solutions of CuI and the bpe ligand [bpe = 1,2-bis(pyridin-4-yl)ethene, C12H10
Externí odkaz:
https://doaj.org/article/7610a72a3e6049b1b6d1aa6f6f93fed4
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 5, Pp 695-697 (2018)
The crystal structure of a platinum(II) supramolecular building block, [Pt(dbbpy)(NCCH3)2](BF4)2 (dbbpy = 4,4′-di-tert-butyl-2,2′-bipyridine, C18H24N2) is an example of a rare head-to-head dimer, even with the bulky tert-butyl groups of the bipyr
Externí odkaz:
https://doaj.org/article/696e58082189479491272db531416ab6
Publikováno v:
IUCrData, Vol 4, Iss 1, p x190122 (2019)
The re-investigated structure of the title compound, [Cu2I2(C12H10N2)]n, a two-dimensional coordination polymer crystallizing with monoclinic (P21/n) symmetry, is based on data collected at 100 K, while the previously reported structure was obtained
Externí odkaz:
https://doaj.org/article/7106acb07f8a4e869c7627b4a9deea4d
Publikováno v:
IUCrData, Vol 4, Iss 1, p x190158 (2019)
In the crystal structure of the title complex, [Pt(C4N2S2)(C10H8N2)], the complex molecules pack as head-to-tail/inversion dimers, which are stabilized by HOMO–LUMO interactions and a Pt...Pt distance of 3.6625 (8) Å. The dimers are linked by C—
Externí odkaz:
https://doaj.org/article/9ae28fda30114a0084fa6c309ab7469a
Publikováno v:
Acta Crystallographica Section E, Vol 68, Iss 9, Pp m1193-m1193 (2012)
In the title compound, [RuCl2(C4H4N2)4]·2CH2Cl2, the RuII atom occupies a position of 222 symmetry and the C atom of the solvent molecule occupies a site with twofold symmetry. The RuII atom has a slightly distorted octahedral geometry. The pyrazine
Externí odkaz:
https://doaj.org/article/35cae7bc494849c39b7994298cb7aca1
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 12, Pp m1702-m1703 (2010)
In the title compound, [PtCl(C27H35N3)]BF4, the PtII atom is in a pseudo-square-planar coordination, which is typical of Pt–terpyridine complexes. The Pt—Cl bond distance is 2.2998 (7) Å. The Pt—N distance of the N atom on the central pyridine
Externí odkaz:
https://doaj.org/article/d821b3ffc0c44a0f83f65b7d724d5646