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pro vyhledávání: '"Bradley W. Musselman"'
Calcium-Ion Binding Mediates the Reversible Interconversion of Cis and Trans Peroxido Dicopper Cores
Autor:
Natasha P. Vargo, Bradley W. Musselman, Nicolai Lehnert, Jill B. Harland, Jerome R. Robinson, Mehmed Z. Ertem
Publikováno v:
Angewandte Chemie (International ed. in English). 60(36)
Coupled dinuclear copper oxygen cores (Cu2 O2 ) featured in type III copper proteins (hemocyanin, tyrosinase, catechol oxidase) are vital for O2 transport and substrate oxidation in many organisms. μ-1,2-cis peroxido dicopper cores (C P) have been p
Autor:
Anastasia C. Manesis, Hannah S. Shafaat, Jason Shearer, Bradley W. Musselman, Brenna C. Keegan, Nicolai Lehnert
Publikováno v:
Inorganic Chemistry. 58:8969-8982
[Image: see text] Nickel-containing enzymes such as methyl coenzyme M reductase (MCR) and carbon monoxide dehydrogenase/acetyl coenzyme A synthase (CODH/ACS) play a critical role in global energy conversion reactions, with significant contributions t
Publikováno v:
Chemical Society reviews. 50(6)
In this Viewpoint, we address some of the limitations within our current understanding of the complex chemistry of the enzymes used in the Nitrogen Cycle. Further understanding of these chemical processes will play a large role in limiting the anthro
Autor:
Bradley W. Musselman, Nicolai Lehnert
Publikováno v:
Chemical communications (Cambridge, England). 56(94)
Catalytically relevant intermediates in carbene transfer reactions from a diazo precursor were investigated using cobalt corrole complexes. Two divergent mechanisms are proposed depending on the oxidation state of the cobalt center. Mechanistically d