Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Bradley M. Kraft"'
Autor:
Bradley M. Kraft, William W. Brennessel, Jordan W. Andrews, Michael T. Viggiani, Nathan F. Kittrell, Matthew T. Heckman
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 3, Pp 318-324 (2024)
The neutral organosilicon(IV) complex, (C6F5)2Si(OPO)2 (OPO = 1-oxopyridin-2-one, C5H4NO2), was synthesized from (C6F5)2Si(OCH3)2 and 2 equiv. of 1-hydroxypyridin-2-one in tetrahydrofuran (THF). Single crystals grown from the diffusion of n-pentane i
Externí odkaz:
https://doaj.org/article/87471d79f4f049048c7bcd094ca9d63d
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 12, Pp 1531-1535 (2015)
The cations in the title salts, [Si(OPO)3]Cl·2CDCl3, (I), [Si(OPO)3]Cl·xCH3CN, (II), and fac-[Si(OPTO)3]Cl·2CDCl3, (III) (OPO = 1-oxo-2-pyridinone, C5H4NO2, and OPTO = 1-oxo-2-pyridinethione, C5H4NOS), have distorted octahedral coordination sphere
Externí odkaz:
https://doaj.org/article/60c480276c7f479db9dbdd165d6aa60f
Publikováno v:
Acta Crystallographica Section E, Vol 68, Iss 7, Pp m893-m893 (2012)
The title compound, [Zr3(C5H5)6Cl2O2], exists as discrete molecules possessing a series of three Cp2Zr units (Cp is cyclopentadienyl) bridged by oxide ligands and end-capped by chloride ligands. The Cp planes in the central and terminal zirconocene u
Externí odkaz:
https://doaj.org/article/7cc9da987e324a509cc181de5cb19b29
Publikováno v:
Organometallics. 41:3522-3537
Publikováno v:
Organometallics. 36:594-604
A series of spirocyclic monoorganosilicon compounds of the form RSi(OPO)2Cl (R = phenyl (1), p-tolyl (2), benzyl (3), Me (4), tBu (5), thexyl (6); OPO = 1-oxo-2-pyridinone) was synthesized and characterized by 1H, 13C, and 29Si NMR spectroscopy, X-ra
Publikováno v:
Organometallics. 33:158-171
A series of neutral organosilicon compounds, R3Si(OPO) (R = Me (1), Et (2), Ph (3)), cis-R2Si(OPO)2 (R = Me (4), Et (5), iPr (6), tBu (7), Ph (9)), (CH2)3Si(OPO)2 (8), and cis-R2Si(OPO)Cl (R = Me (10), Et (11)) (OPO = 1-oxo-2-pyridinone) have been pr
Publikováno v:
Helvetica Chimica Acta. 89:1589-1595
A novel titanium complex with a chelating nitroxide ligand, dichloro-2-{[(hydroxy-κO)phenylamino-κN)phenylmethyl}phenolato(2−)-2κO}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and sing
Autor:
Bradley M. Kraft, William D. Jones
Publikováno v:
Journal of Organometallic Chemistry. 658:132-140
Reaction of CpZrH2 (Cp*, pentamethylcyclopentadienyl) with excess hexafluorobenzene produces a mixture of CpZrHF, C6F5H and CpZr(C6F5)H in ca. 2:1:1 ratio. Reaction of CpZrH2 with excess C6F5H produces a mixture of CpZrHF, CpZr(C6F5)H, CpZr(o -C6F4H)
Publikováno v:
Organometallics. 21:727-731
Cp* 2 ZrH 2 (Cp* = pentamethylcyclopentadienyl) and Hg(C 6 F 5 ) 2 react in pentane to form Cp* 2 Zr(C 6 F 5 )H in high yield at room temperature. Cp* 2 Zr(C 6 F 5 )H reacts intramolecularly at 120 °C under an atmosphere of H 2 togive Cp* 2 Zr(o-C 6
Publikováno v:
Journal of the American Chemical Society. 123:10973-10979
Cp*(2)ZrH(2) (1) (Cp* = pentamethylcyclopentadienyl) reacts with primary, secondary, and tertiary monofluorinated aliphatic hydrocarbons to give Cp*(2)ZrHF (2) and/or Cp*(2)ZrF(2) and alkane quantitatively through a radical chain mechanism. The react