Zobrazeno 1 - 10 of 22 pro vyhledávání: '"Bradley E. Cowie"'
1
Matched ligands for small, stable colloidal nanoparticles of copper, cuprous oxide and cuprous sulfide
Autor: Bradley E. Cowie, Lisa Häfele, Andreas Phanopoulos, Said A. Said, Ja Kyung Lee, Anna Regoutz, Milo S. P. Shaffer, Charlotte K. Williams
This work applies organometallic routes to copper(0/I) nanoparticles and describes how to match ligand chemistries with different material compositions. The syntheses involve reacting an organo-copper precursor, mesitylcopper(I) [CuMes]z (z=4, 5), at
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::57cb56b98f0339fdf5e9302728691088
http://hdl.handle.net/10044/1/104460
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2
Solar Disinfection (SODIS) Provides a Much Underexploited Opportunity for Researchers in Photocatalytic Water Treatment (PWT)
Autor: Neil Robertson, Bradley E. Cowie, Victoria Porley
Publikováno v: Cowie, B E, Porley, V & Robertson, N 2020, ' Solar Disinfection (SODIS) Provides a Much Underexploited Opportunity for Researchers in Photocatalytic Water Treatment (PWT) ', ACS Catalysis, pp. 11779-11782 . https://doi.org/10.1021/acscatal.0c03325
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e539e440aa8aaa84e2ba40044eb2aeb0
https://doi.org/10.1021/acscatal.0c03325
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3
Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged UIV/UIV Pacman complex
Autor: Polly L. Arnold, Laurent Maron, Iskander Douair, Jason B. Love, Bradley E. Cowie
Publikováno v: Chemical Science
Chemical Science, 2020, 11 (27), pp.7144-7157. ⟨10.1039/d0sc02297g⟩
The oxo- and catecholate-bridged UIV/UIV Pacman complex [{(py)UIVOUIV(μ-O2C6H4)(py)}(LA)] A (LA = a macrocyclic "Pacman" ligand; anthracenylene hinge between N4-donor pockets, ethyl substituents on meso-carbon atom of each N4-donor pocket) featuring
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::65d9c950da801b7756f02d62887c5525
https://doi.org/10.1039/d0sc02297g
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5
Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged U
Autor: Bradley E, Cowie, Iskander, Douair, Laurent, Maron, Jason B, Love, Polly L, Arnold
Publikováno v: Chemical Science
A UIV/UIV “Pacman” complex exhibits facile oxo-ligand functionalisation and substitution reactivity, owing to a bridging catecholate ligand that enhances the μ-oxo nucleophilicity and stabilises the resulting products.
The oxo- and catechol
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e541d87397993d321cf92adb83b7ab02
https://pubmed.ncbi.nlm.nih.gov/33033607
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6
M–H–BR3 and M–Br–BR3 interactions in rhodium and nickel complexes of an ambiphilic phosphine–thioether–borane ligand
Autor: Bradley E. Cowie, David J. H. Emslie
Publikováno v: Canadian Journal of Chemistry. 96:484-491
Reaction of [Rh(μ-Cl)(CO)(TXPB)] (1; TXPB = 2,7-di-tert-butyl-5-diphenylboryl-4-diphenylphosphino-9,9-dimethylthioxanthene) with NaBH4 yielded square planar [Rh(μ-H)(CO)(TXPB)] (2) in which the hydride ligand bridges between rhodium and the borane
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0317ee38f408ee0b8b9b73d8f38c2efe
https://doi.org/10.1139/cjc-2017-0758
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7
Reactivity of a Borane-Appended 1,1′-Bisphosphinoferrocene Ligand: Transition Metal and Lewis Acid Coordination, Cyclopentadienyl Ring Borylation, and Boronium Cation Generation
Autor: David J. H. Emslie, Bradley E. Cowie
Publikováno v: Organometallics. 37:1007-1016
The reaction of a borane-appended analogue of 1,1′-bis(phosphino)ferrocene, [Fe(η5-C5H4PPh2)(η5-C5H4PtBu{(o-BPh2)C6H4})] (FcPPB), with [W(CO)6] under photochemical conditions lead to [W(CO)4(FcPPB*)] (1) (FcPPB* = [Fe(η5-C5H4PPh2){η5-C5H3P(tBu)
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d665699af7429067a9be0517e654d2d8
https://doi.org/10.1021/acs.organomet.8b00021
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9
Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U VI O2] 2+
Autor: Bradley E. Cowie, Jamie M. Purkis, Jason B. Love, Jonathan Austin, Polly L. Arnold
Publikováno v: Cowie, B E, Purkis, J M, Austin, J, Love, J B & Arnold, P L 2019, ' Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [U VI O2] 2+ ', Chemical Reviews . https://doi.org/10.1021/acs.chemrev.9b00048
The uranyl ion, [UVIO2]2+, possesses rigorously trans, strongly covalent, and chemically robust Uoxo groups. However, through the use of anaerobic reaction techniques, both one and two-electron reductive functionalization of the uranyl oxo groups hav
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::70a5607ccc75052b8615a2398cbf5182
https://www.pure.ed.ac.uk/ws/files/107533807/20190815_Arnold_UranylOxo_CR_MS_AAV_002_.pdf
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10
Nickel and Palladium Complexes of Ferrocene-Backbone Bisphosphine-Borane and Trisphosphine Ligands
Autor: David J. H. Emslie, Bradley E. Cowie
Publikováno v: Organometallics. 34:4093-4101
Reaction of a ferrocene-backbone bisphosphine-borane ligand, [Fe(η5-C5H4PPh2)(η5-C5H4PtBu{C6H4(BPh2)-o})] (FcPPB), with [Ni(cod)2] (cod = 1,5-cyclooctadiene) or 0.5 equiv of [Pd2(dba)3] (dba = trans,trans-dibenzylideneacetone) afforded [Ni(FcPPB)]
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::eebaa78cfe827b507f9288b34934b62d
https://doi.org/10.1021/acs.organomet.5b00539
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