Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Bradley C, Childs"'
Autor:
Bradley C. Childs, Aiden A. Martin, Aurélien Perron, Emily E. Moore, Yaakov Idell, Tae Wook Heo, Debra L. Rosas, Cherie Schaeffer-Cuellar, Ryan L. Stillwell, Per Söderlind, Alexander Landa, Kiel S. Holliday, Jason R. Jeffries
Publikováno v:
Materials & Design, Vol 192, Iss , Pp 108706- (2020)
Producing gram quantities of uranium metal in a controlled manner by traditional methods is challenging due to the complex chemistry of precursor material and extreme thermal requirements. In this article, a novel approach is reported that combines m
Externí odkaz:
https://doaj.org/article/1a941f1e944341fd83f5ebf0bc0bd95d
Autor:
Maryline G. Ferrier, Bradley C. Childs, Chinthaka M. Silva, Michelle M. Greenough, Emily E. Moore, Andrew J. Swift, Silvina A. Di Pietro, Aiden A. Martin, Jason R. Jeffries, Kiel S. Holliday
Publikováno v:
Inorganic Chemistry. 61:17579-17589
Autor:
Tae Wook Heo, Jason R. Jeffries, Cherie Schaeffer-Cuellar, Aurélien Perron, Chinthaka M. Silva, Aiden A. Martin, Emily E. Moore, Bradley C. Childs, Kiel Holliday, Andrew J. Swift
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 329:1427-1437
Laser-induced heating is increasingly being used for rapid material processing. Here, the decomposition pathways of uranium triiodide and ammonium uranium fluoride during laser irradiation are reported. The experimental results are supported by a sim
Autor:
Bradley C. Childs, Keith V. Lawler, Alfred P. Sattelberger, Daniel S. Mast, Paul M. Forster, Kenneth R. Czerwinski, Frederic Poineau
Publikováno v:
Inorganic Chemistry. 58:5468-5475
The thermal behavior of Tc2O7 has been investigated by single-crystal X-ray diffraction of the solid state over a range of 80–280 K and by ab initio molecular dynamics (MD) simulations. The thermal expansion coefficient of the solid was experimenta
Autor:
Kiel Holliday, Tae Wook Heo, Cherie Schaeffer-Cuellar, Ryan L. Stillwell, Aurélien Perron, Yaakov Idell, Bradley C. Childs, Alexander Landa, Jason R. Jeffries, Aiden A. Martin, Per Söderlind, Emily E. Moore, Debra L. Rosas
Publikováno v:
Materials & Design, Vol 192, Iss, Pp 108706-(2020)
Producing gram quantities of uranium metal in a controlled manner by traditional methods is challenging due to the complex chemistry of precursor material and extreme thermal requirements. In this article, a novel approach is reported that combines m
Autor:
Laurent Bigler, Urs Stalder, Derek R. Peterson, Henrik Braband, Keith V. Lawler, Roger Alberto, Frederic Poineau, Kenneth R. Czerwinski, Paul M. Forster, Alfred P. Sattelberger, Alek Jansen, Bradley C. Childs, Daniel S. Mast
Publikováno v:
European Journal of Inorganic Chemistry. 2018:1137-1144
The oxidation of TcO2 with O2 in the presence of H2O at 250 °C was investigated; Tc2O7 and a red product were observed after the reaction. UV/Visible spectroscopy and a cerium titration on the “red” product are consistent with the presence of a
Autor:
Frederic Poineau, Paul M. Forster, Kenneth R. Czerwinski, Alfred P. Sattelberger, Keith V. Lawler, Bradley C. Childs
Publikováno v:
Chemical Communications. 54:1261-1264
We show that a Tc2O5 molecular species is the likely identity of an unknown volatile oxide which has remained uncharacterized for 50+ years. Exploration of this molecule's absorption spectra and intermolecular self-interactions provides a close match
Autor:
Alfred P. Sattelberger, Bradley C. Childs, Frederic Poineau, Paul M. Forster, Keith V. Lawler, Kenneth R. Czerwinski, Daniel S. Mast
Publikováno v:
Inorganic Chemistry. 56:2448-2458
The molecular and electronic structures of the group 7 heptoxides were investigated by computational methods as both isolated molecules and in the solid-state. The metal–oxygen–metal bending angle of the single molecule increased with increasing
Autor:
Daniel S, Mast, Keith V, Lawler, Bradley C, Childs, Kenneth R, Czerwinski, Alfred P, Sattelberger, Frederic, Poineau, Paul M, Forster
Publikováno v:
Inorganic chemistry. 58(9)
The thermal behavior of Tc
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 306:417-421
Vitrification of sodium pertechnetate into borosilicate glass was performed in air at 1100 °C. A glass with a composition similar to the one developed for vitrification of the low activity waste at the Hanford site was used. A red volatile species w