Výsledky vyhledávání - "Bradley A. Steinhoff"

Carbonylation

Autor: Matthias Beller, Bradley A. Steinhoff, Joseph R. Zoeller, David J. Cole‐Hamilton, Eite Drent, Xiao‐Feng Wu, Helfried Neumann, Shingo Ito, Kyoko Nozaki

Publikováno v: Applied Homogeneous Catalysis with Organometallic Compounds. :91-190

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::94148b2ce0814dc88bc51bce6ae5541f
https://doi.org/10.1002/9783527651733.ch3

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Mechanism of Pd(OAc)2/DMSO-catalyzed aerobic alcohol oxidation: mass-transfer-limitation effects and catalyst decomposition pathways

Autor: Bradley A. Steinhoff, Shannon S. Stahl

Publikováno v: Journal of the American Chemical Society. 128(13)

Pd(OAc)(2) in DMSO is an effective catalyst for the aerobic oxidation of alcohols and numerous other organic substrates. Kinetic studies of the catalytic oxidation of primary and secondary benzylic alcohol substrates provide fundamental insights into

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::70fe42f661177efa4111a9e1d12bc61b
https://pubmed.ncbi.nlm.nih.gov/16569011

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Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation

Autor: Shannon S. Stahl, Amanda E. King, Bradley A. Steinhoff

Publikováno v: The Journal of organic chemistry. 71(5)

Methods for palladium-catalyzed aerobic oxidation of alcohols often benefit from the presence of molecular sieves. This report explores the effect of molecular sieves on the Pd(OAc)2/pyridine and Pd(OAc)2/DMSO (DMSO = dimethyl sulfoxide) catalyst sys

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::90b4399a71c407b4cfe83f1138b105e1
https://pubmed.ncbi.nlm.nih.gov/16496970

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Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence

Autor: Ilia A. Guzei, Shannon S. Stahl, Bradley A. Steinhoff

Publikováno v: Journal of the American Chemical Society. 126(36)

The Pd(OAc)(2)/pyridine catalyst system is one of the most convenient and versatile catalyst systems for selective aerobic oxidation of organic substrates. This report describes the catalytic mechanism of Pd(OAc)(2)/pyridine-mediated oxidation of ben

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44845def917066154a840a0b2bb953ca
https://pubmed.ncbi.nlm.nih.gov/15355108

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Ligand-modulated palladium oxidation catalysis: mechanistic insights into aerobic alcohol oxidation with the Pd(OAc)(2)/pyridine catalyst system

Autor: Shannon S. Stahl, Bradley A. Steinhoff

Publikováno v: Organic letters. 4(23)

Pd(OAc)(2):pyridine (1:4) is an efficient catalyst system for the oxidation of alcohols with molecular oxygen. A mechanistic study of this reaction reveals that pyridine promotes the aerobic oxidation of palladium(0) but inhibits the oxidation of alc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6931534887531cf16f4e9b35b2904194
https://pubmed.ncbi.nlm.nih.gov/12423116

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Mechanistic Study of Alcohol Oxidation by the Pd(OAc)2/O2/DMSO Catalyst System and Implications for the Development of Improved Aerobic Oxidation Catalysts

Autor: Shannon R. Fix, Bradley A. Steinhoff, Shannon S. Stahl

Publikováno v: Journal of the American Chemical Society. 124:766-767

The Pd(OAc)2/O2/DMSO catalyst system displays impressive versatility in the aerobic oxidation of organic substrates, ranging from alcohols to olefins. This report details mechanistic insights into these reactions. Dimethyl sulfoxide (DMSO) plays no r

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0a6ffd0d0e3c18b63e3f46210978cbad
https://doi.org/10.1021/ja016806w

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