Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Brad P. Carrow"'
Autor:
Peng Ren, Zhijie He, Tiantian Xing, Krishna K. Manar, Jessica Sampson, Jian Jin, Long Wang, Brad P. Carrow
Publikováno v:
Advanced Synthesis & Catalysis. 364:3155-3160
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::17dc860831b312396a0802892efb677a
https://doi.org/10.1002/adsc.202200468
https://doi.org/10.1002/adsc.202200468
Publikováno v:
Isr J Chem
This review analyzes recent mechanistic studies that have provided new insights into how the structure of a metal complex influences the rate and selectivity of base-assisted C-H cleavage. Partitioning a broader mechanistic continuum into classes del
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67afa92cafd847adf638b1d8a5cbb7dc
https://doi.org/10.1002/ijch.201900095
https://doi.org/10.1002/ijch.201900095
Zerovalent palladium complexes are ubiquitous active species in modern cross-coupling reactions that comprise many premier methods for the construction of C–C and C–heteroatom bonds in organic synthesis. While palladium(0) complexes stabilized by
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6cbbbe9f49b82538a7a36995b34cbcb7
https://doi.org/10.33774/chemrxiv-2021-477kn
https://doi.org/10.33774/chemrxiv-2021-477kn
Publikováno v:
Chem Commun (Camb)
The origin of switchable site selectivity during Pd-catalysed C–H alkenylation of heteroarenes has been examined through More O’Ferrall–Jencks, isotope effect, and DFT computational analyses, which indicate substitution of ionic thioether for p
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f0dd7842cd5619c861bc2c97edb37c3
https://pubmed.ncbi.nlm.nih.gov/34498633
https://pubmed.ncbi.nlm.nih.gov/34498633
Autor:
Brad P. Carrow, Long Wang
Publikováno v:
ACS Catalysis. 9:6821-6836
Oxidative C–H/C–H coupling is a promising synthetic route for the streamlined construction of conjugated organic materials for optoelectronic applications. Broader adoption of these methods is neve...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::71a2dd4ecbfa56af72e41ef0f71f04bd
https://doi.org/10.1021/acscatal.9b01195
https://doi.org/10.1021/acscatal.9b01195
Autor:
Long, Wang, Brad P, Carrow
Publikováno v:
ACS Catal
Oxidative C–H/C–H coupling is a promising synthetic route for the streamlined construction of conjugated organic materials for optoelectronic applications. Broader adoption of these methods is nevertheless hindered by the need for catalysts that
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::ecd779f72d091f11660a7910df79ea34
https://pubmed.ncbi.nlm.nih.gov/32704402
https://pubmed.ncbi.nlm.nih.gov/32704402
Publikováno v:
ACS Catalysis. 6:4549-4558
The reactions of 2-methyltetrahydropyran (2-MTHP, C6H12O) on Ni2P/SiO2 provide insights on the interactions between a cyclic ether, an abundant component of biomass feedstock, with a transition-metal phosphide, an effective hydrotreating catalyst. At
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b6974c61b7b36c73c7fdb2b78b80e546
https://doi.org/10.1021/acscatal.6b01033
https://doi.org/10.1021/acscatal.6b01033
Publikováno v:
Journal of the American Chemical Society. 138:6392-6395
We report here the remarkable properties of PAd3, a crystalline air-stable solid accessible through a scalable SN1 reaction. Spectroscopic data reveal that PAd3, benefiting from the polarizability inherent to large hydrocarbyl groups, exhibits unexpe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0142377616c01387fb66418af5d6b17c
https://doi.org/10.1021/jacs.6b03215
https://doi.org/10.1021/jacs.6b03215
Publikováno v:
Chemical Science
A new series of palladium catalysts ligated by a chelating bisphosphine monoxide bearing diarylphosphino groups (aryl-BPMO) exhibits markedly higher reactivity for ethylene/methyl acrylate copolymerisation.
A new series of palladium catalysts li
A new series of palladium catalysts li
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::49d646f4371f83078beccddc177e035c
https://doi.org/10.1039/c5sc03361f
https://doi.org/10.1039/c5sc03361f
Publikováno v:
Journal of the American Chemical Society. 139(28)
Thioether ancillary ligands have been identified that can greatly accelerate the C–H alkenylation of O-, S-, and N-heteroarenes. Kinetic data suggest thioether–Pd-catalyzed reactions can be as much as 800× faster than classic ligandless systems.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::776176861e7c9edd8b00153a4312cfa2
https://pubmed.ncbi.nlm.nih.gov/28621936
https://pubmed.ncbi.nlm.nih.gov/28621936