Selectivity of Azine Ligands Toward Lanthanide(III)​/Actinide(III) Differentiation: A Relativistic DFT Based Rationalization

Autor: Abdellah Zaiter, Lotfi Belkhiri, Abdou Boucekkine, Boudersa Amine, Michel Ephritikhine, Yamina Bouzidi

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2014, 53 (9), pp.4687-4697. ⟨10.1021/ic500361b⟩
Inorganic Chemistry, 2014, 53 (9), pp.4687-4697. ⟨10.1021/ic500361b⟩

Polyazines emerge as highly selective ligands toward actinide versus lanthanide separation. Electronic structures of several mono- and polyazine f-complexes of general formula MX3L (M(+3) = Ce, Nd, Eu, U, Am, and Cm; X = RCp(-) or NO3(-); L = N-donor

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https://hal.archives-ouvertes.fr/hal-00992868