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Tuning Zr6Metal-Organic Framework (MOF) Nodes as Catalyst Supports: Site Densities and Electron-Donor Properties Influence Molecular Iridium Complexes as Ethylene Conversion Catalysts

Autor: Yang, D, Odoh, SO, Borycz, J, Wang, TC, Farha, OK, Hupp, JT, Cramer, CJ, Gagliardi, L, Gates, BC

Publikováno v: Yang, D; Odoh, SO; Borycz, J; Wang, TC; Farha, OK; Hupp, JT; et al.(2016). Tuning Zr6Metal-Organic Framework (MOF) Nodes as Catalyst Supports: Site Densities and Electron-Donor Properties Influence Molecular Iridium Complexes as Ethylene Conversion Catalysts. ACS Catalysis, 6(1), 235-247. doi: 10.1021/acscatal.5b02243. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/08g905k3

© 2015 American Chemical Society. The Zr6nodes of the metal-organic frameworks (MOFs) UiO-66 and UiO-67 are metal oxide clusters of atomic precision and can be used as catalyst supports. The bonding sites on these nodes - that is, hydrogen-bonded H2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______325::511f54d9a04369b1c965e29877c44a6a
http://www.escholarship.org/uc/item/08g905k3

Mechanism of oxidation of ethane to ethanol at Iron(IV)-oxo sites in magnesium-diluted Fe2(dobdc)

Autor: Verma, P, Vogiatzis, KD, Planas, N, Borycz, J, Xiao, DJ, Long, JR, Gagliardi, L, Truhlar, DG

Publikováno v: Verma, P; Vogiatzis, KD; Planas, N; Borycz, J; Xiao, DJ; Long, JR; et al.(2015). Mechanism of oxidation of ethane to ethanol at Iron(IV)-oxo sites in magnesium-diluted Fe2(dobdc). Journal of the American Chemical Society, 137(17), 5770-5781. doi: 10.1021/jacs.5b00382. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/2n2732cz

© 2015 American Chemical Society. The catalytic properties of the metal-organic framework Fe2(dobdc), containing open Fe(II) sites, include hydroxylation of phenol by pure Fe2(dobdc) and hydroxylation of ethane by its magnesium-diluted analogue, Fe0

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______325::2132ac13c66df30820c60da6089865af
http://www.escholarship.org/uc/item/2n2732cz