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pro vyhledávání: '"Borislav Bogdanovicć"'
Autor:
Andre Gaidies, Borislav Bogdanovicć, Jacques Rozière, Shijian Liao, Lorraine E. Aleandri, Deborah J. Jones, Alain Michalowicz, Andrea Schott
Publikováno v:
Journal of Organometallic Chemistry. 459:87-93
The stepwise formation of two distinct bimetallic titanium/magnesium complexes during the reduction of TiCl3 (or TiCl4) by magnesium in tetrahydrofuran (THF) has been identified. [TiMgCl2·xTHF] (1) is produced in a first stage, but reacts further wi