Zobrazeno 1 - 10
of 87
pro vyhledávání: '"Boris S. Drach"'
Publikováno v:
Russian Journal of General Chemistry. 80:1345-1350
A convenient preparative procedure has been developed for the synthesis of previously unknown 2-aryl-5-arylsulfanyl-1,3-oxazole-4-carboxylic acids and their functional derivatives from accessible multicenter substrates of the general formula Cl2C=C(N
Autor:
Boris S. Drach, Eduard B. Rusanov, A. P. Kozachenko, Volodymyr Brovarets, O. V. Shablykin, A. N. Vasilenko
Publikováno v:
Russian Journal of General Chemistry. 80:994-1000
The products of addition of amidines to accessible 5-arylamino-4-cyano-1,3-oxazoles at heating in acetic acid undergo recyclization and afford new derivatives of 6-amino-5-acylaminopyrimidin-4-one, whose structure was reliably established using X-ray
Publikováno v:
Russian Journal of General Chemistry. 80:825-828
The accessible two-center electrophilic substrate 4-tosyl-2-phenyl-5-chloro-1,3-thiazole reacts regioselectively with N-, O-, and S-nucleophiles to eliminate a chloride ion. The analog of this substrate, 4-tosyl-2-phenyl-5-p-chlorophenylsulphonyl-1,3
Publikováno v:
Russian Journal of General Chemistry. 80:121-126
Reactions of multicenter electrophilic substrates, 2-aryl-4-dichloromethylidene-1,3-oxazol-5(4H)-ones, with 2-aminopyridine, involved cleavage of the dihydrooxazole ring by the primary amino group of nucleophilic reagent and subsequent cyclization to
Publikováno v:
Russian Journal of General Chemistry. 80:117-120
Reaction of the available 1-tosyl-2,2-dichloroethenyl isothiocyanate with sodium cyanide yields new clearly electrophilic substrate of thiazole nature containing the nitrile group, the tosyl residue, and the chlorine atom at C2, C4, and C5 respective
Publikováno v:
Russian Journal of General Chemistry. 79:1467-1472
Phosphonium ylides stabilized by nitrile and 4,5-di(arylsulfonyl)-1,3-thiazol-2-yl fragments show biphilic reactivity. They react with aromatic aldehydes upon heating revealing a noticeable activity of ylide center and are condensed with typical nucl
Autor:
Boris S. Drach, S. G. Pil’o, Volodymyr Brovarets, V. N. Sviripa, Alexander N. Chernega, V. M. Prokopenko
Publikováno v:
Russian Journal of General Chemistry. 79:496-499
Available polycentral unsaturated azlactones with 4-dichloromethylene group by successive treating with benzamidine and then with morpholine or its analogs were converted to substituted 5-acylamino-4-hydroxypyrimidines containing the residues of the
Publikováno v:
Russian Journal of General Chemistry. 79:500-504
Available chlorine-containing enamides of the general formula Cl2C=CHNHCOR (I) easily react with benzamidine and its derivatives to give 1:1 adducts which under heating with sodium methylate transform to 2-(methoxymethyl)-4,5-diaryl-s-triazines. Reac
Publikováno v:
Russian Journal of General Chemistry. 78:2132-2136
Accessible 2,2-dichloro-1-p-tolylsulfonylethenyl isothiocyanate reacted with hydrazine hydrate to give 5-chloro-2-hydrazino-4-p-tolylsulfonyl-1,3-thiazole whose reactions with thiols and amines followed a complicated pattern. Treatment of 5-chloro-2-
Publikováno v:
Heteroatom Chemistry. 19:677-681
Based on readily available chloralamides, a preparative method for the synthesis of hitherto unknown 2,5-diaryl-3a,6a-dihydro[1,3]thiazolo[4,5-d][1,3]thiazoles with the Lawesson reagent has been elaborated. © 2008 Wiley Periodicals, Inc. Heteroatom