Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Borirane"'
Publikováno v:
Angewandte Chemie. 133:19156-19160
An efficient synthesis of an acid-free neutral oxoborane of the type carboranyl-B(carbene)=O has been developed via a serendipitous discovery from the reaction of 1,2-[BBr(carbene)]-o-carborane with AgOTf. This represents a new type of oxoborane. The
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Autor:
Xin-Yi Du, Quansong Li
Publikováno v:
Chemistry – A European Journal. 26:12891-12897
N,C-chelate organoboron compounds are widely employed as photoresponsive and optoelectronic materials due to their efficient photochromic reactivity. It was found in experiments that two diphenyl-substituted organoboron compounds, namely B(ppy)Ph2 (p
Autor:
Quan-Song Li, Hong-Yang Zhu
Publikováno v:
ChemPhysChem. 21:510-517
As the first discovered organoboron compound with photochromic property, B(ppy)Mes2 (ppy=2-phenylpyridine, Mes=mesityl) displays rich photochemistry that constitutes a solid foundation for wide applications in optoelectronic fields. In this work, we
Publikováno v:
Angewandte Chemie. 131:6755-6759
B(npy)Ar2 (npy=2-(naphthalen-1-yl)pyridine) compounds bearing various nonbulky aryl groups undergo a clean and sequential two-step photoisomerization in which two aryl substituents on boron migrate to a carbon atom of the naphthyl moiety. The second
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Publikováno v:
Angewandte Chemie. 129:9326-9329
A fully reversible photothermal isomerization between carborane-fused trigonal-planar azaborole (dark-purple) and tetrahedral borirane (pale-yellow) has been observed, leading to the isolation and structural characterization of the first example of c
Publikováno v:
Computational and Theoretical Chemistry. 1099:102-108
This research was conducted to answer an important question: which one is important, strain or electronic effects on the aromaticity of three-membered ring annulated benzene? Four indexes were employed to describe the effects of strain rings on the a
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(64)
Boron compounds having a conjugated chelate backbone (N,C-chelate or C,C-chelate) and two mesityl substituents on boron have been found to undergo a facile one-pot transformation/reaction with dienophiles, which leads to the dearomatization of one me
Publikováno v:
Journal of the American Chemical Society. 141(8)
The first ring-opening reactions of ligated boriranes (boracyclopropanes) are described. Treatment of readily available NHC-boriranes bearing ester substituents on the borirane ring with HCl provides stable γ-NHC-bora-γ-lactones in isolated yields