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Strongly Nucleophilic Rh I Centre in Square‐Planar Complexes with Terdentate (κ 3 ) 2,2′:6′,2′′‐Terpyridine Ligands: Crystallographic, Electrochemical and Density Functional Theoretical Studies

Autor: Martin Lutz, Kees Vrieze, Drew McCormack, René de Gelder, Anthony L. Spek, Boke C. de Pater, Evert Jan Baerends, František Hartl, Hans-Werner Frühauf

Publikováno v: European Journal of Inorganic Chemistry. 2004:1675-1686

Rh-I-terpyridine complexes have been unambiguously formed for the first time. The 2,21:6',2"-terpyridine (tpy), 4'-chloro-2,2':6',2"-terpyridine (4'-Cl-tpy) and 4'-(tert-butyldimethylsilyl-ortho-carboranyl)-2,2':6',2"-terpyridine (carboranyl-tpy) lig

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5ab7ef38bec1f7b3c5ddcad8ca60b55a
https://doi.org/10.1002/ejic.200300699

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Crystal structure of the novel neutral octahedral complex [(4 '-(4-tbutylphenyl)-2,2 ': 6 ',2 '-terpyridine)Rh-III(Br)(acetonyl)(2)]

Autor: Peter H. M. Budzelaar, Jan Fraanje, Kees Goubitz, Boke C. de Pater, Anton W. Gal, Kees Vrieze, Hans-Werner Frühauf

Publikováno v: Inorganica Chimica Acta, 358, 431-436
Inorganica Chimica Acta, 358(2), 431-436. Elsevier
Inorganica Chimica Acta, 358, 2, pp. 431-436

The synthesis and the crystal and molecular structure of a unique Rh(III) complex, [Rh III (Br)(acetonyl)2(4 0 -(4-tbutylphenyl)2,2 0 :6 0 ,2 00 -terpyridine)] (1) are described. The yellow crystals separate from the acetone solution of the starting

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f9b9a34e74d49c055947c7a916a53fa4
http://hdl.handle.net/2066/32373

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Synthesis, Structure, and Properties of an Intramolecularly Coordinated Diindacycle: 9,10-Dihydro-9,10-bis[2,6-bis((dimethylamino)methyl)- phenyl]-9,10-diindaanthracene

Autor: Anthony L. Spek, and Otto S. Akkerman, Friedrich Bickelhaupt, Tom Nijbacker, M.A. Dam, Wilberth J. J. Smeets and, Franciscus J. J. de Kanter, Boke C. de Pater

Publikováno v: Organometallics. 16:511-512

o-Phenylenemagnesium (1) was used to prepare the first structurally characterized intramolecularly coordinated diindacycle: 9,10-dihydro-9,10-bis[2,6-bis((dimethylamino)methyl)phenyl]-9,10-diindaanthracene (3).

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2d9a5731d31c93bb7b6e1a2bce07b4bd
https://doi.org/10.1021/om960946a

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Conference

(Re-) configurable real-time operating systems and their applications.

Autor: Boke, C., Gotz, M., Heimfarth, T., El Kebbe, D., Rammig, F.J., Rips, S.

Publikováno v: Proceedings of the Eighth International Workshop on Object-Oriented Real-Time Dependable Systems, 2003 (WORDS 2003); 2003, p148-155, 8p

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Conference

Customizing the configuration process of an operating system using hierarchy and clustering.

Autor: Chivukula, R.P., Boke, C., Rammig, F.J.

Publikováno v: Proceedings Fifth IEEE International Symposium on Object-Oriented Real-Time Distributed Computing (ISIRC 2002); 2002, p280-287, 8p

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Akademický článek

Crystal structure of the novel neutral octahedral complex [(4′-(4-tbutylphenyl)-2,2′:6′,2″-terpyridine)Rh^III(Br)(acetonyl)2]

Autor: de Pater, Boke C.¹, Frühauf, Hans-Werner¹ hwf@science.uva.nl, Goubitz, Kees¹, Fraanje, Jan¹, Budzelaar, Peter H.M.², Gal, Anton W.², Vrieze, Kees¹

Publikováno v: Inorganica Chimica Acta. Jan2005, Vol. 358 Issue 2, p431-436. 6p.

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