Zobrazeno 1 - 8 of 8 pro vyhledávání: '"Blanton R, Gillespie"'
2
Experimental and Computational Studies of Unimolecular 1,1-HX (X = F, Cl) Elimination Reactions of C2D5CHFCl: Role of Carbene:HF and HCl Adducts in the Exit Channel of RCHFCl and RCHCl2 Reactions
Autor: Chaitanya A Patel, Blanton R. Gillespie, Bert E. Holmes, George L. Heard, Donald W. Setser, Mallory M. Rothrock
Publikováno v: The Journal of Physical Chemistry A. 123:2621-2633
The gas-phase unimolecular reactions of C2D5CHFCl molecules with 94 kcal mol-1 of vibrational energy have been studied by the chemical-activation experimental technique and by electronic-structure computations. Products from the reaction of C2D5CHFCl
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9b2862a5311a0e57f3f9ef2e9cdb9e80
https://doi.org/10.1021/acs.jpca.9b00779
Zobrazit plný text záznamu
3
Analysis of the Five Unimolecular Reaction Pathways of CD2ClCHFCl with Emphasis on CD2Cl(F)C: and CD2Cl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination
Autor: Matthew J. Nestler, Timothy M. Brown, Bert E. Holmes, George L. Heard, Donald W. Setser, Blanton R. Gillespie, Caleb A Smith
Publikováno v: The Journal of Physical Chemistry A. 122:8446-8457
The five unimolecular HX and DX (X = F, Cl) elimination pathways of CD2ClCHFCl* were examined using a chemical activation technique; the molecules were generated with 92 kcal mol–1 of vibrational energy in a room-temperature bath gas by a combinati
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::59551f185154fb4b5ed9ca4a425bfff6
https://doi.org/10.1021/acs.jpca.8b06680
Zobrazit plný text záznamu
4
The Unimolecular Reactions of CF3CHF2 Studied by Chemical Activation: Assignment of Rate Constants and Threshold Energies to the 1,2-H Atom Transfer, 1,1-HF and 1,2-HF Elimination Reactions, and the Dependence of Threshold Energies on the Number of F-Atom Substituents in the Fluoroethane Molecules
Autor: Blanton R. Gillespie, Caleb A Smith, Donald W. Setser, George L. Heard, Bert E. Holmes
Publikováno v: The Journal of Physical Chemistry A. 121:8746-8756
The recombination of CF3 and CHF2 radicals in a room-temperature bath gas was used to prepare vibrationally excited CF3CHF2* molecules with 101 kcal mol–1 of vibrational energy. The subsequent 1,2-H atom transfer and 1,1-HF and 1,2-HF elimination r
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ac041eae78db62d63899a197e3ecdf4e
https://doi.org/10.1021/acs.jpca.7b06769
Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání

Omezení vyhledávání
Plný text Recenzováno Digitální knihovna AV ČR
Zdroje