Crystal structure of a dicationic PdII dimer containing a 2-[(diisopropylphosphanyl)methyl]quinoline-8-thiolate pincer ligand

Autor: Arnaud Clerc, Nathalie Saffon-Merceron, Julien Monot, Blanca Martin Vaca, Didier Bourissou

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 1, Pp 18-22 (2022)

A dicationic PdII dimer, bis{2-[(diisopropylphosphanyl)methyl]quinoline-8-thiolato}palladium(II) bis(hexafluoridoantimonate) dichloromethane monosolvate, [Pd2(C32H42N2P2S2)](SbF6)2·CH2Cl2, containing a 2-[(diisopropylphosphanyl)methyl]quinoline-8-th

Externí odkaz: https://doaj.org/article/bfba1f0543fb4f8f9b1cc70c6eaf9115

Base‐Triggered Oxidative Addition to Gold

Autor: Enrico Marelli, Julien Monot, Blanca Martin‐Vaca, Sonia Mallet‐Ladeira, Yago García‐Rodeja, Karinne Miqueu, Didier Bourissou

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, 2023, pp.e202301091. ⟨10.1002/chem.202301091⟩

International audience; The coordination of secondary phosphine oxides (SPO) was shown to efficiently promote the activation of C(sp2)−I bonds by gold, as long as a base is added (NEt3, K2CO3). These transformations stand as a new type of chelation

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aef75dc6291801892ddc4586193f1dc0
https://doi.org/10.1002/chem.202301091

Metal–ligand–Lewis acid multi-cooperative catalysis: a step forward in the Conia-ene reaction

Autor: Arnaud Clerc, Didier Bourissou, Blanca Martin-Vaca, Enrico Marelli, Nicolas Adet, Julien Monot

Publikováno v: Chemical Science

An original multi-cooperative catalytic approach was developed by combining metal–ligand cooperation and Lewis acid activation. The [(SCS)Pd]2 complex featuring a non-innocent indenediide-based ligand was found to be a very efficient and versatile

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7ca2605ea3bcaba91fbbcdccf69bd293

Synthesis and characterization of a NCsp3N pincer complex upon coordination of a bis(pyridine)-functionalized indene

Autor: Volodymyr Vreshch, Julien Monot, Blanca Martin-Vaca, Didier Bourissou

Publikováno v: Polyhedron. 143:49-56

The IndH2(CH2Py)2 1-H pro-ligand has been prepared and its coordination to Pd(II) has been investigated. Mono-lithiation of 1-H gives a symmetric piano-stool complex 2 in which the indenyl ring is η5-coordinated and the two pyridine sidearms are bon

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b331d37b1bfe8fd723e53b0c3a2d15ca
https://doi.org/10.1016/j.poly.2017.07.020

Valorization of CO2: Preparation of 2-Oxazolidinones by Metal–Ligand Cooperative Catalysis with SCS Indenediide Pd Complexes

Autor: Christos E. Kefalidis, Didier Bourissou, Blanca Martin-Vaca, Laurent Maron, Julien Monot, Paul Brunel

Publikováno v: ACS Catalysis
ACS Catalysis, American Chemical Society, 2017, 7 (4), pp.2652-2660. ⟨10.1021/acscatal.7b00209⟩
ACS Catalysis, 2017, 7 (4), pp.2652-2660. ⟨10.1021/acscatal.7b00209⟩
ACS Catalysis, American Chemical Society, 2017, 7 (4), pp.2652--2660

bibtex: ISI:000398986700049 bibtex\location:'1155 16TH ST, NW, WASHINGTON, DC 20036 USA',publisher:'AMER CHEMICAL SOC',type:'Article',affiliation:'Martin-Vaca, B; Bourissou, D (Reprint Author), Univ Toulouse, CNRS, UMR 5069, UPS,LHFA, 118 Route Narbo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa78ec639f740e337f07016c7a8b3cfd
https://doi.org/10.1021/acscatal.7b00209