Zobrazeno 1 - 10
of 217
pro vyhledávání: '"Blaise reaction"'
Publikováno v:
ChemistrySelect. 5:5615-5620
Publikováno v:
New Journal of Chemistry. 44:9010-9017
We have achieved a simple and convenient synthesis of several C(4) substituted 5-ylidenepyrrol-(5H)-ones from 3-aryl/heteroaryl/alkyl 3-cyanopropionates and ethyl/methyl bromoacetates via a useful variation of the classical Blaise reaction. The produ
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Publikováno v:
Synlett. 29:1649-1653
A conceptually new synthesis of pyridine rings by a [C4 + CN] assembly has been developed by applying a vinylogous version of the classic Blaise reaction. The zinc-mediated reaction of (het)aryl or alkyl nitriles with ethyl-4-bromocrotonate provided
Autor:
Bård Helge Hoff
Publikováno v:
Synthesis (Stuttgart)
Acetonitrile is popular as a solvent for performing organic reactions, as a ligand in inorganic chemistry, as a mobile phase in chromatography, and as an electrolyte solvent in dye-sensitized solar cells. This is mainly due to its ability to dissolve
Publikováno v:
Synlett. 29:959-963
This work discloses a novel and efficient protocol for the construction of functionalized chromeno[3,4-c]pyridine derivatives from the Blaise reaction intermediates and 3-cyanocoumarins through a CuCl2-catalyzed sequential Michael addition/intramolec
Autor:
Cyrille Kouklovsky, Stéphanie Courtiol-Legourd, Francelin Bouillère, Jiefang He, Anaïs Zulauf, Ingrid Devillers, Nicolas Auberger, Sylvain Cote des Combes, Christophe Pacaud, Yang Wan, Sophie Thétiot-Laurent, Valérie Alezra, Régis Guillot
Publikováno v:
European Journal of Organic Chemistry. 2018:329-340
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Publikováno v:
European Journal of Organic Chemistry. 2017:4543-4547
The aim of this work is the identification of mild reaction conditions for the Blaise-type transformation of brominated β-keto esters with nitriles to generate enamino-substituted keto esters. The best results were obtained when a combination of ind
Publikováno v:
Synlett. 28:1463-1466
A novel tandem Blaise reaction for the one-pot synthesis of substituted NH-pyrroles was described. The Blaise reaction intermediate, generated in situ from Reformatsky reagent and nitrile, reacted with arylglyoxals chemoselectively to afford a wide v