Asymmetric Organocatalysis – From a Process Development Perspective

Autor: Hao Jiang, Björn Gschwend, Yang Li

Publikováno v: Asymmetric Organocatalysis. :601-631

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::304d8b28f67c34491cd850460e37f70b
https://doi.org/10.1002/9783527832217.ch18

Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage

Autor: Andreas Pfaltz, Marc Liniger, Björn Gschwend, Markus Neuburger, Silvia Schaffner

Publikováno v: Organometallics. 29:5953-5958

Aryl−iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl]2 and secondary phosphine oxide−oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C−P cleavage,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e89768f4d3a1874ede0b6fd1190562d9
https://doi.org/10.1021/om1007874

Asymmetric Formal trans-Dihydroxylation and trans-Aminohydroxylation of α,β-Unsaturated Aldehydes via an Organocatalytic Reaction Cascade

Autor: Signe Grann Hansen, Hao Jiang, Gustav Dickmeiss, Łukasz Albrecht, Karl Anker Jørgensen, Björn Gschwend

Publikováno v: Journal of the American Chemical Society. 132:9188-9196

This study demonstrates the first formal asymmetric trans-dihydroxylation and trans-aminohydroxylation of alpha,beta-unsaturated aldehydes in an organocatalytic multibond forming one-pot reaction cascade. This efficient process converts alpha,beta-un

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::47db8a9b3dc586a35d80aa437fc35c57
https://doi.org/10.1021/ja103538s

ChemInform Abstract: Asymmetric Trienamine Catalysis for the Construction of Structurally Rigid Cyclic α,α-Disubstituted Amino Acid Derivatives

Autor: Hao Jiang, Lukasz Albrecht, Karl Anker Joergensen, Björn Gschwend, Signe Grann Hansen

Publikováno v: ChemInform. 42

In the presence of a secondary amine catalyst, 2,4-dienals undergo highly regio- and stereoselective Diels—Alder reactions with olefinic azlactones.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::caef26af807f1fdeeb9f9952ec897559
https://doi.org/10.1002/chin.201152123

Asymmetric trienamine catalysis for the construction of structurally rigid cyclic α,α-disubstituted amino acid derivatives

Autor: Karl Anker Jørgensen, Łukasz Albrecht, Hao Jiang, Björn Gschwend, Signe Grann Hansen

Publikováno v: Jiang, H, Gschwend, B, Albrecht, L, Hansen, S G & Jørgensen, K A 2011, ' Asymmetric Trienamine Catalysis for the Construction of Structurally Rigid Cyclic α,α-Disubstituted Amino Acid Derivatives ', Chemistry: A European Journal, vol. 17, no. 33, pp. 9032-9036 . https://doi.org/10.1002/chem.201101539

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0ba1e1c68c6f3d0758d9ce876f0e6c40
https://pubmed.ncbi.nlm.nih.gov/21744409