Zobrazeno 1 - 10
of 26
pro vyhledávání: '"Birgit Weberndörfer"'
Publikováno v:
Organometallics. 22:744-758
While the dinuclear compounds [(η 6 -mes)Os{κ 1 -OC(O)CF 3 (μ-Cl)] 2 (2) and [(η 6 -mes)Os{κ 1 -OS(O) 2 CF 3 }(μ-Cl)] 2 (3), prepared from [(η 6 -mes)OsCl(η 3 -C3H5)] (1) and CF 3 CO 2 H or CF 3 SO 3 H by elimination of propene, are not suita
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 628:2383-2394
Der Cyclooctadien-Komplex [Rh(η4-C8H12)(κ2-tBu2AsCH2PiPr2)](PF6) (1a) reagiert mit CO und CNtBu zu den Substitutionsprodukten [Rh(L)2(κ2-tBu2AsCH2PiPr2)](PF6) (2, 3. Aus 1a und Na(acac) entsteht in Gegenwart von CO die Neutralverbindung [Rh(κ2-ac
Publikováno v:
Organometallics. 21:2369-2381
The mixed-ligand complex [IrCl(C2H4)(SbiPr3)(PiPr3)] (2), prepared from [IrCl(C2H4)(PiPr3)]2 (1) and SbiPr3, reacts not only with CO, diphenylacetylene, and H2 by ligand substitution or oxidative addition but also with diaryldiazomethanes R2CN2 to gi
Publikováno v:
European Journal of Inorganic Chemistry. 2002:1076-1080
The dinuclear cyclooctadienediylruthenium(IV) compound [{RuCl2(η3:η3-C10H16)}2] (1) reacts with PCy3 in 2-propanol under an H2 atmosphere to give the hydrido(dihydrogen) complex [RuHCl(H2)(PCy3)2] (2) in nearly quantitative yield. Treatment of 1 wi
Autor:
Helmut Werner, Birgit Weberndörfer
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :1479-1486
The reaction of the areneosmium(II) compunds [Os(η6-arene)(L)X2] 2a–2e, 3, 4 with propargylic alcohols HCCCR2(OH) (where R = phenyl or p-tolyl) in the presence of AgPF6 leads to the formation of the cationic osmium allenylidenes [Os(η6-arene)(CCC
Publikováno v:
Organometallics. 20:3672-3685
The reaction of the dichloro(vinylidene)ruthenium compounds [RuCl2(CCHR)L2] (R = Ph or tBu and L = PCy3 or PiPr3) (1a−d) with [H(OEt2)2]BArf (BArf- = [B{C6H3(CF3)2-3,5}4]-) resulted in the attack of the proton at the Cβ carbon atom of the vinylide
Publikováno v:
Journal of Organometallic Chemistry. :502-510
Neutral diphenylcarbenerhodium(I) complexes of the general composition trans -[RhX(CPh 2 )(P i Pr 3 ) 2 ] (X=F ( 3 ), OCN ( 4 ), CF 3 CO 2 ( 5 ), PhCO 2 ( 6 ), CF 3 SO 3 ( 7 )) were prepared from the chloro or bromo precursors trans -[RhCl(CPh
Publikováno v:
Angewandte Chemie. 112:3392-3395
Publikováno v:
Angewandte Chemie International Edition. 39:3266-3269
Publikováno v:
Journal of Organometallic Chemistry. 607:182-193
The bis(η3-2-methylallyl)ruthenium(II) complexes [Ru(η3-2-MeC3H4)2(κ2-R2PCH2PPh2)] (R=iPr 2, Cy 3) were prepared from the cycloocta-1.5-diene derivative [Ru(η3-2-MeC3H4)2(η4-C8H12)] (1) and the unsymmetrical bis(phosphino)methanes R2PCH2PPh2 (R=