Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Bimal Pudasaini"'
Autor:
Pavel Zatsepin, Jun-Hyeong Kim, Michael R. Gau, Patrick J. Carroll, Bimal Pudasaini, Mu-Hyun Baik, Daniel J. Mindiola
Publikováno v:
Journal of the American Chemical Society. 144:13066-13070
Highly modular and rational syntheses of titanium compounds containing ditelluride, terminal telluride, and bis(telluride) structural motifs are disclosed in this study. Titanate anions bearing two
Autor:
Mehrafshan G. Jafari, David M. Kaphan, Jeremy Kropf, Yerin Park, Takashi Kurogi, Daniel J. Mindiola, Bimal Pudasaini, Patrick J. Carroll, Mu-Hyun Baik, Massimiliano Delferro
Publikováno v:
Angew Chem Int Ed Engl
A low-spin and mononuclear vanadium complex, ((Me)nacnac)V(CO)(η(2)–P≡C(t)Bu) (2) ((Me)nacnac(−) = [ArNC(CH(3))](2)CH, Ar = 2,6-(i)Pr(2)C(6)H(3)), was prepared upon treatment of the vanadium neopentylidyne complex ((Me)nacnac)V≡C(t)Bu(OTf) (
Publikováno v:
Journal of the American Chemical Society. 143:13428-13440
The cationic Ru-H complex [(C6H6)(PCy3)(CO)RuH]+BF4- (1) was found to be an effective catalyst for the dehydrative C-H coupling reaction of phenols and aldehydes to form 2-alkylphenol products. The coupling reaction of phenols with branched aldehydes
Publikováno v:
Chemical science. 13(36)
A typical synthetic protocol for preparing 7-azaindoles involves the coupling of 2-aminopyridine and alkyne substrates using a Rh(iii)-catalyst. The catalysis requires the assistance of an external Ag
Autor:
Mu-Hyun Baik, Gérard Jaouen, William E. Geiger, Bimal Pudasaini, Kan Wu, Siden Top, Ji Young Park
Publikováno v:
Organometallics
Organometallics, American Chemical Society, 2020, 39 (5), pp.679-687. ⟨10.1021/acs.organomet.9b00822⟩
Organometallics, American Chemical Society, 2020, 39 (5), pp.679-687. ⟨10.1021/acs.organomet.9b00822⟩
The oxidations of 1,1′-di-p-anisolyl-2-cymantrenylbutene (3b) and 1,1′-di-p-hydroxyphenyl-2-cymantrenylbutene (3c) were investigated by electrochemical and spectroscopic experiments and by density ...
Autor:
Bimal Pudasaini
Publikováno v:
Organometallics. 38:1091-1098
Single-site yttrium catalysts have the ability to produce poly(dialkyl vinyl phosphonate) with a very narrow molecular weight distribution. Following the report of Rieger and co-workers ( J. Am. Ch...
Autor:
Bimal Pudasaini, Hendrik F. T. Klare, Lukas Omann, Martin Oestreich, Elisabeth Irran, Mu-Hyun Baik
Publikováno v:
Chemical Science. 9:5600-5607
An in-depth experimental and theoretical study of the substituent exchange reaction of silylium ions is presented. Apart from the substitution pattern at the silicon atom, the selectivity of this process is predominantly influenced by the counteranio
Autor:
Ludger P. Stubbs, Martin van Meurs, Choon Heng Low, Alexander Genest, Bimal Pudasaini, Lili Zhao, Notker Rösch, James D. Nobbs
Publikováno v:
ACS Catalysis. 7:7070-7080
The palladium-catalyzed conversion of (bio)pentenoic acid isomers (PEAs) occurs with high activity and selectivity to adipic acid (ADA) in the presence of the diphosphine ligand L2 = 1,2-bis[(di-tert-butyl)phosphinomethyl]benzene (DTBPX) and an acid
Autor:
Seihwan Ahn, Daniel J. Mindiola, Pavel Zatsepin, Bimal Pudasaini, Michael R. Gau, Mu-Hyun Baik
Publikováno v:
Chemical communications (Cambridge, England). 55(13)
Cp*(Me3P)Ir(CH3)(OTf), a complex known to reversibly activate CH4 and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H2CPPh3 in THF to afford two major species [Cp*(Me3P)(Ph3P)Ir(CH2CH3)][OTf] and [Cp*(Me3P)Ir(H)(η2-CH2CH
Autor:
Benjamin G. Janesko, Bimal Pudasaini
Publikováno v:
Organometallics. 33:84-93
The selectivity of transition-metal-catalyzed alkyl cross-coupling is significantly affected by agostic interactions. We report a systematic computational study of how ligand trans influence affects the strength of β-agostic interactions in Ni(II)