Vibrational Circular Dichroism Detects Symmetry Breaking due to Conformational Mobility in C2-Symmetry Chiral Molecules and Provides Further Insight into Inter-Chromophoric Interactions

Autor: David A. Lightner, Giovanna Longhi, Stefan E. Boiadjiev, Giuseppe Mazzeo, Sergio Abbate

Publikováno v: Symmetry, Vol 12, Iss 1752, p 1752 (2020)
Symmetry
Volume 12
Issue 11
Symmetry (Basel) 12 (2020): 1752-1–1752-13. doi:10.3390/sym12111752
info:cnr-pdr/source/autori:Mazzeo, Giuseppe; Abbate, Sergio; Boiadjiev, Stefan E.; Lightner, David A.; Longhi, Giovanna/titolo:Vibrational Circular Dichroism Detects Symmetry Breaking due to Conformational Mobility in C-2-Symmetry Chiral Molecules and Provides Further Insight into Inter-Chromophoric Interactions/doi:10.3390%2Fsym12111752/rivista:Symmetry (Basel)/anno:2020/pagina_da:1752-1/pagina_a:1752-13/intervallo_pagine:1752-1–1752-13/volume:12

Bicyclo[3.3.1]nonane-2,6-dione (1) and bicyclo[3.3.1]nona-3,7-diene-2,6-dione (2) have been examined by vibrational circular dichroism (VCD), which, as for most C2-symmetric systems, exhibits strong VCD signals. In the case of 2, VCD signals are stro

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a7d6e4545dd015827acb7b9d2872ef4
https://www.mdpi.com/2073-8994/12/11/1752

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