1D and 3D coordination polymers based on the Cu 3 ( μ 3 -OH)( μ -pz) 3 and Cu(Hpz) 3 SBUs connected by the flexible glutarate dianion

Autor: Corrado Di Nicola, C. Pettinari, Massimo Gazzano, Magda Monari, Luciano Pandolfo, Arianna Lanza, Enrico Forlin, Fabrizio Nestola

Publikováno v: Inorganica Chimica Acta (Testo stamp.) 470 (2018): 385–392. doi:10.1016/j.ica.2017.09.004
info:cnr-pdr/source/autori:Forlin, Enrico; Lanza, Arianna; Di Nicola, Corrado; Monari, Magda; Gazzano, Massimo; Nestola, Fabrizio; Pettinari, Claudio; Pandolfo, Luciano/titolo:1D and 3D coordination polymers based on the Cu3<%2Finf>(?3<%2Finf>-OH)(?-pz)3<%2Finf> and Cu(Hpz)3<%2Finf> SBUs connected by the flexible glutarate dianion/doi:10.1016%2Fj.ica.2017.09.004/rivista:Inorganica Chimica Acta (Testo stamp.)/anno:2018/pagina_da:385/pagina_a:392/intervallo_pagine:385–392/volume:470

[object Object]Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(? 3-OH)(?-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz=pyrazole) secondary building units (SBUs), bridged by

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67a8f8261202e7a65f2b7bf6f1401fa6
http://hdl.handle.net/11577/3300974

Coordination polymers based on trinuclear and mononuclear copper-pyrazolate building moieties connected by fumarate or 2-methylfumarate ions

Autor: Corrado Di Nicola, Enrico Forlin, Arianna Lanza, Luciano Pandolfo, Fabrizio Nestola, Federica Garau, Marta Maria Natile, Claudio Pettinari

Publikováno v: Journal of organometallic chemistry
714 (2012): 74–80. doi:10.1016/j.jorganchem.2012.03.026
info:cnr-pdr/source/autori:Di Nicola C.; Forlin E.; Garau F.; Lanza A.; Natile M.M.; Nestola F.; Pandolfo L.; Pettinari C./titolo:Coordination polymers based on trinuclear and mononuclear copper-pyrazolate building moieties connected by fumarate or 2-methylfumarate ions/doi:10.1016%2Fj.jorganchem.2012.03.026/rivista:Journal of organometallic chemistry (Print)/anno:2012/pagina_da:74/pagina_a:80/intervallo_pagine:74–80/volume:714

By reacting water solutions of pyrazole (Hpz) with copper(II) fumarate or 2-methylfumarate in solvothermal conditions two almost identical trinuclear triangular complexes, [Cu3(μ3-OH)(μ-pz)3{R(COO)2}(Hpz)], [R = CH CH, C(CH3) CH], have been obtaine

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0cbfc51fe194867971d22ab9daaf09cd
http://hdl.handle.net/11577/2515583

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