Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Bernard Bocquet"'
Autor:
Xavier Melich, Craig J. Matthews, Gérald Bernardinelli, Bernard Bocquet, Alan F. Williams, Simon Verdan, Francine Lavergnat, Anita Kübel-Pollak, Pierre-Yves Morgantini
Publikováno v:
New J. Chem.. 30:851-860
The conformational preferences of protonated 2-benzimidazole cations have been modelled. Non-alkylated benzimidazoles show no strong conformational preferences, but methylation at the N1 position leads to high rotational barriers. The crystal structu
Publikováno v:
Chemistry - A European Journal. 9:1062-1074
The introduction of long semirigid spacers between the capping carbon atom of the tripod and the unsymmetrical tridentate binding units provides the novel, extended covalent podand tris-[2-[2-(6-diethylcarbamoylpyridin-2-yl)-1-ethyl-1H-benzoimidazol-
Autor:
Johan Varin, Jean-François Lemonnier, Sébastien Floquet, Laure Guénée, Amir Hossein Zaim, Bertrand Donnio, Emmanuel Terazzi, Claude Piguet, Bernard Bocquet, Emmanuel Cadot, Thibault Dutronc, Benoît Heinrich
Publikováno v:
European Journal of Inorganic Chemistry. 2013
Publikováno v:
Inorganic Chemistry. 35:1332-1337
The reactivity of the hydroperoxo complex [Co(CN)(5)OOH](3)(-) has been studied in aqueous solution. The complex undergoes acid-catalyzed aquation (k = 1.89(5) x 10(-)(2) s(-)(1), pK(a) = 5.21(4), T = 20 degrees C, I = 0.1 M). Assuming an I(d) mechan
Publikováno v:
Angewandte Chemie. 107:618-621
Publikováno v:
Inorganic Chemistry, Vol. 51, No 18 (2012) pp. 10012-10024
This work illustrates a simple approach for deciphering and exploiting the various free energy contributions to the global complexation process leading to the binuclear triple-stranded podates [Ln(2)(L9)](6+) (Ln is a trivalent lanthanide). Despite t
Publikováno v:
Journal of the American Chemical Society, Vol. 116, No 20 (1994) pp. 9092-9102
The segmental bidentatetridentate ligand 5-{2”[6”-( 1”'-(3,5- imethoxybenzyl)- 1'”H-benzimidazol-2”'- yl)-pyridin-2”-yl] - 1' -methyl- 1' H-benzimidazol-5'-ylmethy1l- 1 - methyl-2-(6””- ethylpyridine-2””-yl)- 1H -b enzimidazole (L
Publikováno v:
Inorganic Chemistry. 33:4112-4121
Dublished in Aduance ACS Abstracts, July 15, 1994. Lindsey,‘J. S. New J . Chem. 1991, 15, 153-180. (a) Lehn, J.-M. Angew. Chem., Int. Ed. Engl. 1990,29,1304-1319. (b) Baxter, P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Seel, C.;
Publikováno v:
Helvetica Chimica Acta, Vol. 77, No 4 (1994) pp. 931-942
The development of a modified Phillips reaction allows the synthesis of complicated heteroleptic ligands based on pyridine and 1H-benzimidazole moieties. The key-step formation of aromatic 1H-benzimidazole rings from N-(2-nitroaryl)arenecarboxamides
Autor:
Claude Piguet, Daniel Emery, Jean-François Lemonnier, Emmanuel Terazzi, Johan Varin, Bernard Bocquet, Jiri Mareda, Laure Guenee
Publikováno v:
Chemistry-A European Journal, Vol. 17, No 1 (2011) pp. 184-195
The axial connection of flexi- ble thioalkyls chains of variable length (n = 1-12) within the segmental bis-tri- dentate 2-benzimidazole-8-hydroxyqui- noline ligands (L12 Cn � 2H ) 2� provides amphiphilic receptors designed for the synthesis of n