Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes

Autor: Marc Schmidtmann, Florian Jaroschik, Manfred Penkhues, Emmanuel Nicolas, Radhakrishnan Kokkuvayil Vasu, Malte Fischer, Dominique Harakat, Agathe Martinez, Jean-Luc Vasse, Fabien Massicot, Rüdiger Beckhaus, Bernard Bahlmann

Publikováno v: Organometallics
Organometallics, American Chemical Society, 2017, 36 (10), pp.2004-2013. ⟨10.1021/acs.organomet.7b00213⟩

International audience; The reaction of low-valent zirconocene reagents formedeither from the Negishi reagent Cp2Zr(n-butyl)2 or from the reduction ofCp2ZrCl2 with Mg with various pentafulvenes yielded the firstzirconocene−pentafulvene complexes, C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0245d107ab79ba904d983a8c5792aee7
https://doi.org/10.1021/acs.organomet.7b00213