Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Berit Bartik"'
Publikováno v:
Journal of the American Chemical Society. 122:810-822
Reaction of the butadiynyl complex (η5-C5Me5)Re(NO)(PPh3)(C⋮CC⋮CH) (ReC4H) with Cu(OAc)2 (pyridine, 80 °C) gives the μ-octatetraynediyl complex ReC8Re (70%). Analogous cross-coupling of ReC4H and ReC2H gives (after chromatography) ReC4Re (14%)
Publikováno v:
Angewandte Chemie International Edition in English. 35:414-417
Autor:
John A. Gladysz, Berit Bartik, Atta M. Arif, Monika Brady, Tamás Bartik, Weiqing Weng, James A. Ramsden
Publikováno v:
Journal of the American Chemical Society. 117:11922-11931
One major objective has been the preparation of compounds in which sp carbon chains span two metals, L{sub n}M(C){sub x}M`L`{sub n`} (I). There are now many examples of such C{sub 2} complexes. However, higher homologs remain much less well explored.
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 98:117-122
The novel optically active phosphine, bis(8-phenyloctyl) (Menth) phosphine, (Menth = 1R,3R,4S( - )menthyl) is synthesized and sulfonated under mild conditions to yield the corresponding sulfonated phosphine, disodium bis-(8-(para-sulfonatophenyl)octy
Autor:
Tamas Bartik, Barbara B. Bunn, William R. Bebout, Brian E. Hanson, Thomas E. Glass, Berit Bartik
Publikováno v:
Journal of Molecular Catalysis. 94:157-161
Phosphorus-31 spin lattice relaxation times, T1's, for SAP hydroformylation catalysts derived from HRh (CO) (TPPTS)3 and TPPTS (TPPTS = trisulfonated triphenyl phosphine trisodium salt) are consistent with a liquid-like character for the supported aq
Publikováno v:
Journal of Organometallic Chemistry. 480:15-21
The electron donating water soluble phosphines, P{(CH 2 ) n C 6 H 4 - p -SO 3 Na} 3 , n = 1, 2, 3 and 6, react rapidly with Co 2 (CO) 8 under two phase reaction conditions to yield the disproportionation products, [Co(CO) 3 (P{(CH 2 ) n C 6 H 4 - p -
Publikováno v:
Journal of Molecular Catalysis. 88:43-56
The electron donating, water soluble phosphines, P[ (CH 2 ) x C 6 H 4 - p -SO 3 3Na] 3 , x =1, 2, 3, 6, are used to generate aqueous rhodium catalysts for the hydroformylation of octene-1. At low L/ Rh ratios conversion generally increases with incre
Publikováno v:
Inorganic Chemistry. 33:164-169
Direct sulfonation of bis(diphenylpbospbino)ethane, DPPE, leads to a complianted mixture of sulfonated products which includes 1,2-bis[bis(m-sodiosulfonatophenyl)phosphino]ethane, DPPETS. DPPETS is isolated in gram quantities by fractional precipitat
Publikováno v:
Scopus-Elsevier
The synthesis and characterization of a series of water-soluble cobalt carbonyl complexes is described: HCo(CO) 3 (TPPTS), HCo(CO) 2 (TPPTS) 2 , and [Co(CO) 3 (TPPTS)] - , where TPPTS=P(m-C 6 H 4 SO 3 Na) 3 . Investigation of the substitution of Co 2
Publikováno v:
Journal of Molecular Catalysis. 85:121-129
Water is seen to have a dramatic effect on the alcohol/aldehyde distribution in the P (nBu) 3 modified cobalt carbonyl catalyzed hydroformylation of 1-octene. In particular the rate of alcohol synthesis is greater in the presence of water. Under the