Zobrazeno 1 - 10
of 95
pro vyhledávání: '"Benzotrichloride"'
Publikováno v:
Chemical Communications. 56:11945-11948
A B12 complex–BODIPY dyad was synthesized by peripheral modification of cobalamin derivatives. The photophysical properties of the dyad were investigated by UV-vis, PL, and transient absorption spectroscopy. A visible light-driven dechlorination re
Autor:
Hisashi Shimakoshi, Yoshio Hisaeda, Kenji Imamura, Zhongli Luo, Kazunari Yoshizawa, Yoshihito Shiota
Publikováno v:
The Journal of organic chemistry. 86(8)
A convergent paired electrolysis catalyzed by a B12 complex for the one-pot synthesis of a tertiary amide from organic trichlorides (R-CCl3) has been developed. Various readily available organic trichlorides, such as benzotrichloride and its derivati
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Publikováno v:
The Journal of organic chemistry. 84(12)
A catalytic system for the chlorination of alcohols under Appel conditions was developed. Benzotrichloride is used as a cheap and readily available chlorinating agent in combination with trioctylphosphane as the catalyst and phenylsilane as the termi
Publikováno v:
Chemical Physics Letters. 634:118-121
We report spectroscopic observations of the α,α-dichlorobenzyl radical obtained by corona excited supersonic jet expansion using a pinhole-type glass nozzle. Vibronically excited but jet-cooled radicals were generated by corona discharge of the pre
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 45(25)
The electrolysis of benzotrichloride at −0.9 V vs. Ag/AgCl in the presence of the B12 model complex, heptamethyl cobyrinate perchlorate, in ethanol under aerobic conditions using an undivided cell equipped with a platinum mesh cathode and a zinc pl
Autor:
Hisashi Shimakoshi, Yoshio Hisaeda
Publikováno v:
ChemInform. 47
An oxygen switch in catalysis of the cobalamin derivative (B12 )-TiO2 hybrid catalyst for the dechlorination of trichlorinated organic compounds has been developed. The covalently bound B12 on the TiO2 surface transformed trichlorinated organic compo
Publikováno v:
Rubber Chemistry and Technology. 80:365-377
Partially cyclized deproteinized natural rubber (DPNR) in latex form was successfully prepared by using a combination of sulfuric acid (H2SO4) and benzotrichloride (PhCCl3) in the presence of Terric 320 as a non-ionic surfactant. The main parameters
Autor:
Hisashi Shimakoshi, Yoshio Hisaeda
Publikováno v:
Angewandte Chemie (International ed. in English). 54(51)
An oxygen switch in catalysis of the cobalamin derivative (B12 )-TiO2 hybrid catalyst for the dechlorination of trichlorinated organic compounds has been developed. The covalently bound B12 on the TiO2 surface transformed trichlorinated organic compo
Publikováno v:
Synthetic Communications. 35:2715-2722
High‐yield reductive homocoupling of benzotrichloride and benzal chloride followed by consecutive reductive dechlorination to 1,2‐dichlorostilbene and stilbene is effected in the presence of sodium formate as the reducing agent and Pd/C catalysts