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Autor:
Benjamin Wardzinski, Dilraj K. Judge, Julia Schaefer, Marko Weimar, Ingo Krossing, Matthew J. Fuchter
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 41(27)
We have unambiguously demonstrated the binding of the silver(I) ion in the central cavity of [7]-helicene, given that the counterion is weakly coordinating. In such a binding mode, the helicene is functioning as a chiral molecular tweezer.