Zobrazeno 1 - 10
of 36
pro vyhledávání: '"Benjamin M. Day"'
Publikováno v:
Angewandte Chemie. 134
Replacing a monoanionic cyclopentadienyl (Cp) ligand in dysprosium single-molecule magnets (SMMs) with a dianionic cyclobutadienyl (Cb) ligand in the sandwich complexes [(η4-Cb′′′′)Dy(η5-C5Me4tBu)(BH4)]− (1), [(η4-Cb′′′′)Dy(η8-P
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::022ab536482807b79ba03058454d78f8
https://doi.org/10.1002/ange.202200525
https://doi.org/10.1002/ange.202200525
Autor:
Fu-Sheng Guo, Richard A. Layfield, Benjamin M. Day, Yan-Cong Chen, Akseli Mansikkamäki, Ming-Liang Tong
Publikováno v:
Science
Breaking through the nitrogen ceiling Single-molecule magnets could prove useful in miniaturizing a wide variety of devices. However, their application has been severely hindered by the need to cool them to extremely low temperature using liquid heli
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0163f024e88925b253b6fc8f657ce310
https://doi.org/10.1126/science.aav0652
https://doi.org/10.1126/science.aav0652
Autor:
Richard A. Layfield, Anindita Chakraborty, James P. Durrant, Mian He, Jinkui Tang, Benjamin M. Day
Publikováno v:
Durrant, J 2020, ' Double Ligand Activation in Silyl-Substituted Rare-Earth Cyclobutadienyl Complexes ', Organometallics . https://doi.org/10.1021/acs.organomet.9b00763
Organometallics
Organometallics
The sodium cyclobutadienyl (Cb) reagent [Na2{η4-C4(SiMe3)4}(THF)]2 (2) reacts with rare-earth halides [MCl3(THF)x], where M = Y, Dy (x = 3.5) and Lu (x = 3), giving the sandwich coordination polymers [M{η3-C4(SiMe3)4H}{η4-C4(SiMe3)3-κ-(CH2SiMe2}N
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a17e2ea3641359f8ce6929cf45aeee76
Autor:
Fu-Sheng Guo, Benjamin M. Day, Yan-Cong Chen, Ming-Liang Tong, Akseli Mansikkamäki, Richard A. Layfield
Publikováno v:
Angewandte Chemie International Edition
ion of a chloride ligand from the dysprosium metallocene [(Cpttt)2DyCl] (1Dy Cpttt=1,2,4‐tri(tert‐butyl)cyclopentadienide) by the triethylsilylium cation produces the first base‐free rare‐earth metallocenium cation [(Cpttt)2Dy]+ (2Dy) as a sa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c5d0ef4944ca7787c5132940f0fdb63
https://doi.org/10.1002/anie.201705426
https://doi.org/10.1002/anie.201705426
Publikováno v:
Dalton Transactions. 45(28):11301-11305
The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the is
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4eb803d4bb43503f46a07c9b59a08d1
https://doi.org/10.1039/C6DT02486F
https://doi.org/10.1039/C6DT02486F
Autor:
Yan-Cong Chen, Akseli Mansikkamäki, Ming-Liang Tong, Richard A. Layfield, Benjamin M. Day, Fu-Sheng Guo
Publikováno v:
Angewandte Chemie International Edition. 59:18844-18844
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::21e94dc579d048ee881317344b4925c8
https://doi.org/10.1002/anie.202010617
https://doi.org/10.1002/anie.202010617
Autor:
Fu-Sheng Guo, Yan-Cong Chen, Akseli Mansikkamäki, Richard A. Layfield, Benjamin M. Day, Ming-Liang Tong
Publikováno v:
Angewandte Chemie. 132:19004-19004
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6b92b81482cc571245f3b4dc61b78263
https://doi.org/10.1002/ange.202010617
https://doi.org/10.1002/ange.202010617
Autor:
Akseli Mansikkamäki, Fu-Sheng Guo, Akira Sekiguchi, Benjamin M. Day, Richard A. Layfield, Sean Giblin
Publikováno v:
Chemistry-A European Journal
The potassium cyclobutadienyl [K2{η4‐C4(SiMe3)4}] (1) reacts with MCl3(THF)3.5 (M=Y, Dy) to give the first rare‐earth cyclobutadienyl complexes, that is, the complex anions [M{η4‐C4(SiMe3)4}{η4‐C4(SiMe3)3‐κ‐(CH2SiMe2}]2−, (2M), as t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::70d1653d05f4a0876a63aaf09f93cd15
https://orca.cardiff.ac.uk/id/eprint/115334/1/Layfield_et_al-2018-Chemistry_-_A_European_Journal.pdf
https://orca.cardiff.ac.uk/id/eprint/115334/1/Layfield_et_al-2018-Chemistry_-_A_European_Journal.pdf
Publikováno v:
Accounts of Chemical Research
CONSPECTUS: The discovery of materials capable of storing magnetic information at the level of single molecules and even single atoms has fueled renewed interest in the slow magnetic relaxation properties of single-molecule magnets (SMMs). The lantha
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::436034effb8afbcb353661c6ba0ff0df
https://pubmed.ncbi.nlm.nih.gov/30091896
https://pubmed.ncbi.nlm.nih.gov/30091896
Publikováno v:
Organometallics. 34:2348-2355
Deprotonation of dimethyl(pyrrolidylmethyl)silylpentadiene (5) and bis(2-methoxyethyl)aminomethyl(dimethyl)silylpentadiene (7) with nBuLi/tmeda and nBuLi, respectively, results in their corresponding lithium complexes, 6 and 8. The lithium cation in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::83d1a9a91824165493dedc77aad2bf54
https://doi.org/10.1021/om501144f
https://doi.org/10.1021/om501144f