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pro vyhledávání: '"Benjamin Leotard"'
Autor:
Hiromi Okamoto, Takahide Fukuyama, Benjamin Leotard, Ilhyong Ryu, Yuki Higashibeppu, Célia Brancour
Publikováno v:
Synlett. 24:2287-2291
Ruthenium complex [RuCl2(CO)3]2 catalyzes the addition of 1,3-diketones to terminal alkynes. We observed C-addition with acyclic 1,3-diketones, whereas the use of cyclic 1,3-diketones systematically led to O-addition reactions.
Autor:
Yuki Higashibeppu, Hiromi Okamoto, Benjamin Leotard, Ilhyong Ryu, Célia Brancour, Takahide Fukuyama
Publikováno v:
ChemInform. 45
Acyclic 1,3-diketones undergo Ru-catalyzed reaction with terminal alkynes to yield C-addition products whereas cyclic 1,3-diones give O-addition products under similar conditions.