Zobrazeno 1 - 10
of 49
pro vyhledávání: '"Benjamin J. Lear"'
Publikováno v:
Molecules, Vol 23, Iss 5, p 1234 (2018)
The photothermal effect of nanoparticles has proven efficient for driving diverse physical and chemical processes; however, we know of no study addressing the dependence of efficacy on nanoparticle size. Herein, we report on the photothermal effect o
Externí odkaz:
https://doaj.org/article/fbd83cd79c8c4813af42eef064f3a843
Publikováno v:
Langmuir. 38:10810-10816
Publikováno v:
Macromolecules. 55:7232-7239
The Marcus model forms the foundation for all modern discussion of electron transfer (ET). In this model, ET results in a change in diabatic potential energy surfaces, separated along an ET nuclear coordinate. This coordinate accounts for all nuclear
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa02bd02448b23823a82e48c0986aff2
https://doi.org/10.26434/chemrxiv-2022-253hc
https://doi.org/10.26434/chemrxiv-2022-253hc
Autor:
Vadim Tanygin, Benjamin J. Lear
Publikováno v:
Chemistry of Materials. 33:63-72
Iridium, platinum, and gold nanoparticles, protected with sulfur, selenium, or tellurium dodecane ligands, were synthesized under ambient laboratory conditions. These nine nanoparticles were charac...
Publikováno v:
ACS nano. 16(3)
Ligand-stabilized colloidal metallic nanoparticles are prized in science and technology for their electronic properties and tunable surface chemistry. However, little is known about the interplay between these two aspects of the particles. A particul
Autor:
Benjamin J. Lear, Jonathan W. Fagan
Publikováno v:
The Journal of Physical Chemistry C. 124:24435-24440
Electron spin resonance (ESR) spectroscopy is used to probe the electronic properties of the metallic cores of small (∼2 nm) gold nanoparticles protected by 1-hexanethiol and 1-dodecanethiol, suspe...
Autor:
Benjamin J. Lear, Andrea L. Widstrom
Publikováno v:
Applied Nanoscience. 10:819-825
We demonstrate the ability of photothermal heating by hexanethiol-protected gold nanoparticles to drive a retro Diels–Alder reaction in an 8.47 mM 1,1,2,2-tetrachloroethane solution of the adduct formed between furan and maleic anhydride. We find t
Autor:
Emma N. Van Burns, Benjamin J. Lear
Publikováno v:
The Journal of Physical Chemistry C. 123:14774-14780
The photothermal effect of nanoparticles has proven to be an effective means of substantially increasing the rate of chemical transformations, by factors of up to 109. For thermally activated proce...
Publikováno v:
Macromolecules. 52:3839-3844
Though it is known that the photothermal effect of nanoparticles can be used to greatly increase the rate of polymer curing, at present, little is known about how the parameters of photothermal curing affect the desirable chemical and physical proper