Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Benjamin Alan Anderson"'
Publikováno v:
Inorganica Chimica Acta. 220:215-231
The aldol reactions of tetracarbonyl(phosphine)methyl(methoxy)methylene chromium complexes and pentacarbonylmethyl (dialkylamino)methylene chromium complexes with aldehydes and ketones were examined. The reactions of the phosphine complexes give only
Autor:
Timothy A. Brandvold, Jianming Bao, Yao Chang Xu, Benjamin Alan Anderson, Cynthia A. Challener, William D. Wulff, Arnold L. Rheingold
Publikováno v:
Journal of the American Chemical Society. 115:10671-10687
The reactions of 1-(4-hexynyl)methoxymethylenepentacarbonyl complexes 11 of the group 6 metals with alkynes lead to phenol and cyclopentenedione products, both of which are the result of cyclization with one molecule of the external alkyne and the in
Publikováno v:
Journal of the American Chemical Society. 115:4602-4611
The first Michael addition reactions of the anions of aminocarbene complexes to α,β-unsaturated carbonyl compounds are reported. Unlike their corresponding amide enolates, these anions give exclusive 1,4-addition to a number of enones. For chiral c
Autor:
Cynthia A. Challener, Steven Chamberlin, Stephen D. Darling, Christopher K. Murray, Benjamin Alan Anderson, Katherine L. Faron, Dominic C. Yang, Oak K. Kim, William D. Wulff, Yao Chang Xu
Publikováno v:
Journal of the American Chemical Society. 115:1359-1376
The reactions of alkyl chromium carbene complexes with alkynes have been found to give cyclopentenones. Mechanisms are proposed to account for the formation of these products that involve metal hydride intermediates. As has been previously reported f
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 23
The objective of this study has been to elucidate the mechanism of the rhodium(I)-catalyzed hydroboration process. Evidence that the reaction proceeds through a multistep pathway analogous to that of transition metal catalyzed olefin hydrogenation is
Autor:
Arnold L. Rheingold, Sandra Tribbitt, William D. Wulff, Benjamin Alan Anderson, Timothy S. Powers
Publikováno v:
ChemInform. 24
The first examples of intermolecular Diels-Alder reactions of aminocarbene complexes are described. Various members of both the alkylamino and acylamino families of complexes are investigated. The E-isomer of [tran-propenyl(methylamino)methylene]pent
Publikováno v:
ChemInform. 24
Autor:
Stephen D. Darling, Cynthia A. Challener, Oak K. Kim, Steven Chamberlin, Katherine L. Faron, William D. Wulff, Dominic C. Yang, Christopher K. Murray, Benjamin Alan Anderson, Yao Chang Xu
Publikováno v:
ChemInform. 24
The reactions of alkyl chromium carbene complexes with alkynes have been found to give cyclopentenones. Mechanisms are proposed to account for the formation of these products that involve metal hydride intermediates. As has been previously reported f
Publikováno v:
ChemInform. 24
The first Michael addition reactions of the anions of aminocarbene complexes to α,β-unsaturated carbonyl compounds are reported. Unlike their corresponding amide enolates, these anions give exclusive 1,4-addition to a number of enones. For chiral c