Zobrazeno 1 - 10
of 96
pro vyhledávání: '"Benjamin A. DeGraff"'
Autor:
Alison M. Whitehurst, Carl Trindle, James N. Demas, Benjamin A. DeGraff, Jennifer L. Bon, Michael Z. Snow, Eileen N. Dixon
Publikováno v:
Inorganic Chemistry. 51:3355-3365
A suite of Ru(II) complexes in which one ligand is pH responsive and the other two are varied in an effort to achieve improved photophysics has been synthesized and their potential as pH reporters assessed. The more general purpose of the study was t
Publikováno v:
Langmuir. 27:9567-9575
A suite of luminescent Re(I) complexes has been prepared whose emissive properties are responsive to the probe's local environment. These complexes were embedded in a series of chemically similar polymers whose room temperature rigidity varied over a
Publikováno v:
Applied Spectroscopy. 63:437-441
Luminescence lifetimes are widely used as an analysis tool. Since decays in analytical systems are frequently complex decays rather than single exponentials, apparent lifetime methods based on the rapid lifetime determination (RLD) method or single f
Publikováno v:
Applied Spectroscopy. 61:1238-1245
Water quenching of luminescent [Ru(phen)2dppz]Cl2, [Ru(phen)2 dppn]Cl2, and [Ru(4,7-Ph2phen)2dppz]Cl2 (phen = 1,10-phenanthroline; 4,7-Ph2phen = 4,7-diphenyl-1,10-phenanthroline; dppz = dipyrido[3, 2-a:2′3′-c]phenazine; dppn = benzodipyrido(a:3,2
Publikováno v:
Coordination Chemistry Reviews. 251:546-553
The inclusion of a series of luminescent Re(I) complexes in α- and β-cyclodextrin in water is described. The complex's general structure is [L 2 Re(CO) 3 (4-R-pyridine)][ClO 4 ] where L 2 represents the α-diimine ligands 2,2′-bipyridine or 1,10
Publikováno v:
Inorganic Chemistry. 44:6662-6669
A series of luminescent transition metal complexes using the pH-sensitive ligand 5-carboxy-1,10-phenanthroline has been synthesized and characterized. The complexes, based on Ru(II) and Re(I), show monotonic changes in both luminescent intensity and
Publikováno v:
Applied Spectroscopy. 58:603-607
For evaluating exponential luminescence decays, there are a variety of computational rapid integral methods based on the areas of the decay under different binned intervals. Using both Monte Carlo methods and experimental photon counting data, we com
Publikováno v:
Applied Spectroscopy. 57:532-537
An adaptation of square-wave gated phase-modulation (GPM) fluorimetry allows for self-referenced intensity measurements without the complexity of dual excitation or dual emission wavelengths. This AC technique utilizes square-wave excitation, gated d
Publikováno v:
Analytical Chemistry. 74:4821-4827
A new gated form of phase fluorometry for measuring lifetimes is presented. The technique uses a square-wave excitation and gates the detector on only during the off period of the excitation. Using a long-lived sample, this eliminates or reduces erro
Publikováno v:
Applied Spectroscopy. 56:167-173
Oxygen and copper(II) ion quenching studies were conducted on a model sensor system to elucidate the significant, yet not fully characterized, role of polymer supports in sensor performance. The system consisted of [Ru(Ph2phen)2(4-cyclamCH2(4′-Me)b