Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Ben-Fa Chu"'
Publikováno v:
ACS macro letters. 7(2)
A left-handed helical poly(phenyl isocyanide) bearing a norbornene unit and a Pd(II) complex on each terminus was prepared. The norbornene terminus was core cross-linked with a bisnorbornene linker via ring-opening metathesis polymerization (ROMP), y
Publikováno v:
Angewandte Chemie (International ed. in English). 60(2)
Inspired by the exquisite helices in Nature, fabrication of helical materials with controlled handedness has attracted considerable attention. Herein, we report on precis synthesis of single left- and right-handed helical polyisocyanides through livi
Publikováno v:
ACS Macro Letters. 6:824-829
A novel enantiopure phenyl isocyanide (1) carrying l-proline derivative was designed and synthesized. Living polymerization of 1 using a alkyne-Pd(II) catalyst affording a series of helical poly-1ms with controlled molecular weights (Mns) and narrow