Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Beáta Vilhanová"'
Autor:
Jiří Václavík, Petr Šot, Jan Pecháček, Beáta Vilhanová, Ondřej Matuška, Marek Kuzma, Petr Kačer
Publikováno v:
Molecules, Vol 19, Iss 6, Pp 6987-7007 (2014)
The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(η6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively develop
Externí odkaz:
https://doaj.org/article/b71536ee9a0947d183726de5ee3c1951
Publikováno v:
Molecules, Vol 18, Iss 6, Pp 6804-6828 (2013)
This review is oriented toward the asymmetric transfer hydrogenation (ATH) of imines regarding mostly fundamental, yet important topics from the practical point of view. Development of analytical methods for the monitoring of ATH (i.e., kinetics and
Externí odkaz:
https://doaj.org/article/418512882d9f4e218025ada5ebdf51ee
Autor:
Antonio Togni, Beáta Vilhanová, Luca Artiglia, Jeroen A. van Bokhoven, Jiří Václavík, Marco Ranocchiari
Publikováno v:
ACS Catalysis. 7:3414-3418
Subnanometer (d = 0.8 ± 0.2 nm) gold particles homogeneously dispersed on amino-functionalized silica catalyze Glaser-type alkyne coupling, providing corresponding 1,3-diynes under mild conditions. Readily available λ3-iodane PhI(OAc)2 is used as a
Publikováno v:
Advanced Synthesis & Catalysis. 359:677-686
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 231:531-539
New chiral imide-oxazoline derivatives of Kemp’s acid were synthesized with the aim to produce new ligands suitable for catalytic asymmetric reactions. Compound 1 is C18H28N2O3, systematic name (1R, 5S, 7R)-7-[(S)-4-tert-butyl-4,5-dihydrooxazole-2-
Autor:
Marek Kuzma, Petr Kačer, Jiří Václavík, Radka Hrdličková, Miloš Mikoška, Jan Pecháček, Ondřej Matuška, Beáta Vilhanová, Jakub Zápal
Publikováno v:
Reaction Kinetics, Mechanisms and Catalysis. 118:215-222
The role of the sulfonamide moiety of Noyori-Ikariya [Ru(II)Cl(η 6-p-cymene)(S,S)-(N-arylsulfonyl-DPEN)] (where DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes in the asymmetric transfer hydrogenation (ATH) of imines (1-methyl-3,4-d
Autor:
Jaroslav Maixner, Jakub Zápal, Petr Kačer, Marek Kuzma, Jiří Václavík, Richard Pažout, Beáta Vilhanová, Jan Pecháček, Petr Šot
Publikováno v:
Chemical Communications. 52:362-365
A method for enantioselective hydrogenation of cyclic imines with gaseous hydrogen has been developed. Easily accessible Noyori-Ikariya Ru(II) and Rh(III) complexes can be used directly without an inert atmosphere. Substrate activation has been achie
Publikováno v:
ChemCatChem. 8:308-312
The use of nonprotic solvents (e.g., dichloromethane, toluene) increases the enantioselectivity of the asymmetric hydrogenation of olefins with chiral [Rh(Me-BPE)(cod)]OTf [Me-BPE=1,2-bis(2,5-dimethylphospholano)ethane; cod=1,5-cyclooctadiene; OTf=tr
Publikováno v:
Tetrahedron: Asymmetry. 25:1346-1351
Only four types of dimeric precursors [RuCl2(η6-arene)]2 for the synthesis of Noyori’s half sandwich diamine catalysts [RuCl(TsDPEN)(η6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems
Autor:
Ondřej Matuška, Marek Kuzma, Petr Kačer, Beáta Vilhanová, Jan Pecháček, Jiří Václavík, Petr Šot
Publikováno v:
Molecules
Molecules, Vol 19, Iss 6, Pp 6987-7007 (2014)
Molecules, Vol 19, Iss 6, Pp 6987-7007 (2014)
The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(η6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively develop