Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Bart J. Dahl"'
Publikováno v:
Tetrahedron Letters. 58:4703-4708
Two triply lactone-bridged 1,3,5-triphenylbenzene derivatives with solubilizing moieties have been synthesized in five and six steps from commercially available starting materials. Compounds containing the 1,3,5-triphenylbenzene core with two atom br
Publikováno v:
Tetrahedron Letters. 61:152429
3,10-Bis(triethylene glycol)benzo[1,2-c:4,5-c']bis[2]benzopyran-5,12-dione has been synthesized as an example of a dilactone-bridged p-terphenyl with a C2h crankshaft architecture that exhibits significant fluorescence. Lactone-bridged rotationally r
Autor:
Eva M. Charlesworth-Seiler, Bart J. Dahl, Joel G. Patrow, Deidra L. Gerlach, Eric W. Reinheimer, Jonathan P. Kitzrow, Samantha M. Meyer
Publikováno v:
Tetrahedron. 76:131222
This report describes the synthesis of five new colorful 6-aryldibenzo[b,d]pyrylium cation salts, a largely unexplored structural unit. These rare compounds are benzannulated structural derivatives of the well-known flavylium cations found widespread
Publikováno v:
Tetrahedron. 71:283-292
Three highly fluorescent dilactone bridged terphenyls with crankshaft architectures have been synthesized. This general class of compounds is relatively unexplored. These compounds have been characterized by fluorescence and UV–vis spectroscopy. Fo
Publikováno v:
Tetrahedron Letters. 53:6245-6249
The physical properties of biaryl-containing compounds are known to be highly dependent on molecular geometry. We report the syntheses and fundamental spectroscopic study of two donor–acceptor biaryl lactone (6H-benzo[c]chromen-6-one) pH-driven swi
Autor:
Jennifer L. Hartmann, Nancy S. Mills, Francine E. Cheng, Bart J. Dahl, Sean P. McClintock, Kiran C. Patel, Joseph M. Baylan, Cornelia Tirla
Publikováno v:
The Journal of Organic Chemistry. 76:645-653
Dications of 9-(3-phenyl-1H-inden-1-ylidene)-5H-dibenzo[a,d]cycloheptene, 5(2+), were prepared by oxidation with SbF(5) in SO(2)ClF, and their magnetic behavior was compared to dications of 9-(3-phenyl-1H-inden-1-ylidene)-9H-fluorene, 2(2+). The good
Autor:
Bart J. Dahl, Nancy S. Mills
Publikováno v:
Journal of the American Chemical Society. 130:10179-10186
Derivatives of the dication of tetrabenzo[5.5]fulvalene were prepared with phenyl and ethynyl spacers through ionization of the appropriate bis-methylethers. The antiaromaticity shown by the parent dication was demonstrated for these dications with s
Publikováno v:
Tetrahedron Letters. 46:8359-8362
Net directed 180° bond rotation was achieved through diastereoselective ring-opening reactions in an achiral biaryl lactone using a chiral nucleophile followed by re-lactonization. The efficiency of the directed bond rotation has been determined by
Autor:
Bruce P. Branchaud, Bart J. Dahl
Publikováno v:
Tetrahedron Letters. 45:9599-9602
A class of chiral biaryl molecules that have been designed to undergo unidirectional rotation about the aryl–aryl bond may show promise for future application in the area of synthetic molecular motors. These asymmetric molecules should be capable o
Publikováno v:
Tetrahedron Letters. 53:6433-6435
This preliminary report describes the synthesis of three 6-aryldibenzo[b,d]pyrylium salts, a relatively unexplored structural unit. The optical and spectroscopic properties of the 6-aryldibenzo[b,d]pyrylium salts were examined as a function of pH. Al