Zobrazeno 1 - 10
of 1 661
pro vyhledávání: '"Barry M. Trost and"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 12, Iss 1, Pp 1136-1152 (2016)
A full account of our efforts toward an asymmetric redox bicycloisomerization reaction is presented in this article. Cyclopentadienylruthenium (CpRu) complexes containing tethered chiral sulfoxides were synthesized via an oxidative [3 + 2] cycloaddit
Externí odkaz:
https://doaj.org/article/5784d11790c942d886af96cf5f2c63ca
Publikováno v:
Chemical Science
An efficient palladium-catalyzed AAA reaction with a simple α-sulfonyl carbon anion as nucleophiles is presented for the first time. Allyl fluorides are used as superior precursors for the generation of π-allyl complexes that upon ionization libera
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0216b8df1eff40c14c98ed114379ec4c
https://doi.org/10.1039/d1sc02599f
https://doi.org/10.1039/d1sc02599f
Autor:
Barry M. Trost, Zhiwei Jiao
Publikováno v:
Journal of the American Chemical Society. 142:21645-21650
A novel palladium-mediated carbonylogous 1,4-dipole was developed by in situ deprotonation. By using our own-developed C2-unsymmetric phosphoramidite as supporting ligand, this dipole was applied to the asymmetric synthesis of chiral cyclohexanones v
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1a887953dbbb9fd910fee4291ac16bdd
https://doi.org/10.1021/jacs.0c11535
https://doi.org/10.1021/jacs.0c11535
Autor:
Barry M. Trost, Chuanle Zhu
Publikováno v:
Organic Letters. 22:9683-9687
The enantioselective Mannich reaction of 2H-azirines with alkynyl ketones is achieved under Zn-ProPhenol catalysis, delivering various aziridines with vicinal tetrasubstituted stereocenters in high...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c7c2c08dd282118e277204d87b456ebb
https://doi.org/10.1021/acs.orglett.0c03737
https://doi.org/10.1021/acs.orglett.0c03737
Publikováno v:
Chemistry – A European Journal. 26:15354-15377
The efficient and selective synthesis of functionalized seven-membered rings remains an important pursuit within synthetic organic chemistry, as this motif appears in numerous drug-like molecules and natural products. Use of cycloaddition reactions r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dbb3be304c44862f69053b240e2b05dc
https://doi.org/10.1002/chem.202002713
https://doi.org/10.1002/chem.202002713
Publikováno v:
Journal of the American Chemical Society. 142:18628-18636
Design and exploration of new intermediates for chemo-, regio-, and stereoselective cycloadditions remain a formidable challenge in modern organic synthesis. Compared to the well-developed 1,3-dipolar cycloadditions, Pd-catalyzed1,4-dipolar cycloaddi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::465ed4c800c5ccc76fba477f893c599e
https://doi.org/10.1021/jacs.0c08348
https://doi.org/10.1021/jacs.0c08348
Publikováno v:
ACS Catalysis. 10:9496-9503
Quaternary carbon stereocenters are ubiquitous in a wide variety of organic compounds and drug molecules. Highly enantioselective construction of such quaternary carbon centers poses a singular cha...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f2621bd63695581587248a09aaa612d9
https://doi.org/10.1021/acscatal.0c02861
https://doi.org/10.1021/acscatal.0c02861
Publikováno v:
Nature Chemistry. 12:629-637
Polyketide natural products are an important class of biologically active compounds. Although substantial progress has been made on the synthesis of repetitive polyketide motifs through the iterative application of a single reaction type, synthetic a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2369eec3d9c4c13b6e8020317b055e06
https://doi.org/10.1038/s41557-020-0464-x
https://doi.org/10.1038/s41557-020-0464-x
Autor:
Barry M. Trost, Chang Min
Publikováno v:
Nature Chemistry. 12:568-573
Nature's synthetic plans to construct molecules have been developed over millions of years of evolution and frequently prove to be among the most sophisticated. Mimicking nature's route can be a direct and feasible way for synthetic organic chemists
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::893b02d0fa4026f45aa37410abd59cc5
https://doi.org/10.1038/s41557-020-0439-y
https://doi.org/10.1038/s41557-020-0439-y
Publikováno v:
Angewandte Chemie. 132:4268-4291
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fcc42d12345c1659475069e0a7b190c9
https://doi.org/10.1002/ange.201909692
https://doi.org/10.1002/ange.201909692