Photoactivation of titanium-oxo cluster \left[Ti_{6}O_{6}(OR)_{6}(O_{2}C^{t}BU)_{6}\right]$ : mechanism, photoactivated structures, and onward reactivity with O₂ to a peroxide complex

Autor: Brown, Stephen E., Mantaloufa, Ioanna, Andrews, Ryan T., Barnes, Thomas J., Lees, Martin R., De Proft, Frank, Cunha, Ana, Pike, Sebastian D.

Publikováno v: Chemical science

The molecular titanium-oxo cluster [Ti6O6((OPr)-Pr-i)(6)((O2CBu)-Bu-t)(6)] (1) can be photoactivated by UV light, resulting in a deeply coloured mixed valent (photoreduced) Ti (iii/iv) cluster, alongside alcohol and ketone (photooxidised) organic pro

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https://hdl.handle.net/10067/1927350151162165141

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Synthesis of a nanoscale Cu(II)31-oxo-carboxylate cluster, and effect of Cu–oxo cluster size on visible-light absorption.

Autor: Barnes, Thomas J., Payne, Jack, Pike, Sebastian D.

Publikováno v: Chemical Communications; 1/4/2023, Vol. 59 Issue 1, p59-62, 4p

STORAGE POWER OPTIMIZATIONS FOR CLIENT DEVICES AND DATA CENTERS.

Autor: Hung-Ching Chang¹, Kruus, Erik², Barnes, Thomas J.³, Agrawal, Abhishek R.⁴, Cameron, Kirk W.¹

Publikováno v: Intel Technology Journal. 2012, Vol. 16 Issue 3, p172-193. 22p. 4 Diagrams, 4 Charts, 7 Graphs.

Photoactivation of titanium-oxo cluster [Ti 6 O 6 (OR) 6 (O 2 C ^t Bu) 6 ]: mechanism, photoactivated structures, and onward reactivity with O 2 to a peroxide complex.

Autor: Brown SE; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Mantaloufa I; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Andrews RT; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Barnes TJ; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk., Lees MR; Department of Physics, University of Warwick Coventry UK., De Proft F; Research Group of General Chemistry (ALGC), Vrije Universiteit Brussel (VUB) Brussels Belgium ana.cunha@uantwerpen.be., Cunha AV; Research Group of General Chemistry (ALGC), Vrije Universiteit Brussel (VUB) Brussels Belgium ana.cunha@uantwerpen.be.; University of Antwerp Antwerp Belgium., Pike SD; Department of Chemistry, University of Warwick Coventry UK sebastian.pike@warwick.ac.uk.

Publikováno v: Chemical science [Chem Sci] 2022 Dec 07; Vol. 14 (3), pp. 675-683. Date of Electronic Publication: 2022 Dec 07 (Print Publication: 2023).