The stable silylene Si[(NCH2But)2C6H4-1,2]: Reactions with Group 14 element halides

Autor: Peter B. Hitchcock, Barbara Gehrhus, Helen Jansen

Publikováno v: Journal of Organometallic Chemistry. 691:811-816

Reaction of the thermally stable silylene Si[(NCH 2 Bu t ) 2 C 6 H 4 -1,2] ( 1 ) [abbrev. as Si(NN)] with SiX 4 (X = Cl or Br) afforded the disilanes (NN)SiX(SiX 3 ) and [(NN)SiX] 2 (X = Br only), the trisilane (NN)SiX-[(SiX 3 )Si(NN)] and the monosi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2fe7551747eb5c0ebd2e6a83d06ee8c5
https://doi.org/10.1016/j.jorganchem.2005.10.027

Synthetic and Structural Studies on the Cyclic Bis(amino)stannylenes Sn[(NR)2C10H6-1, 8] and their Reactions with SnCl2 or Si[(NCH2But)2C6H4-1, 2] (R = SiMe3 or CH2But)

Autor: Anthony G. Avent, Barbara Gehrhus, Christian Drost, Peter B. Hitchcock, Michael F. Lappert

Publikováno v: Zeitschrift f�r anorganische und allgemeine Chemie. 630:2090-2096

Treatment of {HNR}2C10H6-1, 8 [R = SiMe3 (1), CH2But (2)] with Sn[N(SiMe3)2]2 afforded the cyclic stannylene Sn[{NR}2C10H6-1, 8] [R = SiMe3 (3), CH2But (4)]. From 3 and SnCl2 in THF and crystallisation from toluene, the product was the crystalline te

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https://doi.org/10.1002/zaac.200400319

Synthesis and characterisation of bis(amino)silylene–nickel(0), –palladium(II), –platinum(0), –platinum(II) and copper(I) complexes

Autor: Anthony G. Avent, Michael F. Lappert, Hieronim Maciejewski, Barbara Gehrhus, Peter B. Hitchcock

Publikováno v: Journal of Organometallic Chemistry. 686:321-331

The bis(amino)silylene Si[(NCH2tBu)2C6H4-1,2] ( SiNN) behaved as a ligand in displacing COD or PPh3 from [Ni(COD)2], [Pt(PPh3)4] or [CuI(PPh3)3], yielding the crystalline d10 complexes [Ni(SiNN)4] (crystallised from Et2O as the 1:1-adduct 2), [Pt(

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https://doi.org/10.1016/s0022-328x(03)00560-6

Synthesis and Structure of an Azatrisilacyclobutane and Its Precursor, a Novel Lithium Enamide Having a Tricyclic (LiNSiO)2 Skeleton

Autor: Peter B. Hitchcock, Michael F. Lappert, Floria Antolini, Barbara Gehrhus

Publikováno v: Angewandte Chemie International Edition. 41:2568-2571

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d650b55e393779678453bec831811926
https://doi.org/10.1002/1521-3773(20020715)41:14<2568::aid-anie2568>3.0.co

The stable silylene Si[(NCH2tBu)2C6H4-1,2]: insertion into LiC or LiSi bonds of lithium alkyls LiR or [LiSi(SiMe3)3(THF)3] [R=Me, tBu or CH(SiMe3)2]

Autor: Xiaoping Cai, Barbara Gehrhus, Michael F. Lappert, J. Chris Slootweg, Peter B. Hitchcock

Publikováno v: Journal of Organometallic Chemistry, 643-644, 272-277. Elsevier
Cai, X P, Gehrhus, B, Hitchcock, P B, Lappert, M F & Slootweg, J C 2002, ' The stable silylene Si[((NCH2Bu)-Bu-t)(2)C6H4-1,2]: insertion into Li-C or Li-Si bonds of lithium alkyls LiR or [LiSi(SiMe3)(3)(THF)(3)] [R = Me, Bu-t or CH(SiMe3)(2)] ', Journal of Organometallic Chemistry, vol. 643-644, pp. 272-277 . https://doi.org/10.1016/S0022-328X(01)01273-6

The new crystalline amino-functionalised lithium silyls Li[Si{(NCH2tBu)2C6H4-1,2}R](L) [R=Si(SiMe3)3 (sisyl), L=(THF)2 (2); R=Me, L=(OEt2)2 (3); R=tBu, L=(THF)3 (4a) or THF(OEt2) (4b); R=CH(SiMe3)2, L=(THF)2 (5)] have been obtained in high yield from

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ede44a28c52750d08258eb1a94a4188c
https://doi.org/10.1016/s0022-328x(01)01273-6