Synthesis, Structural, Magnetic, and Redox Properties of Asymmetric Diiron Complexes with a Single Terminally Bound Phenolate Ligand. Relevance to the Purple Acid Phosphatase Enzymes

Autor: Elisabeth Lambert, Geneviève Chottard, Michel Bardet, Jean Marc Latour, Azzedine Bousseksou, Alain Deronzier, Jean-Pierre Tuchagues, Jean Laugier, Barbara Chabut, Sylvie Chardon-Noblat

Publikováno v: Journal of the American Chemical Society. 119:9424-9437

New asymmetrical ligands (H2L) have been synthesized to provide both a bridging and a terminal phenolate to a pair of iron ions in order to mimic the binding of a single terminal tyrosinate at the diiron center of the purple acid phosphatases. H2L1 i

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::13dde5007cf2466d1affbb45b3b54253
https://doi.org/10.1021/ja970345q

Spectroscopic and Electrochemical Characterizations of an Aqua Ligand Exchange and Oxidatively-Induced Deprotonation in Diiron Complexes

Autor: Sylvie Chardon-Noblat, Olivier Horner, Barbara Chabut, Frédéric Avenier, Noëlle Debaecker, Peter Jones, Pecaut Jacques, Lionel Dubois, Claudine Jeandey, Jean-Louis Oddou, Alain Deronzier, Jean-Marc Latour

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2004, 43, pp.1638-1648
Inorganic Chemistry, 2004, 43, pp.1638-1648
HAL

International audience; Reaction of the unsymmetrical phenol ligand 2-((bis(2-pyridylmethyl)amino)methyl)-6-(((2-pyridylmethyl)benzylamino)methyl)-4-methylphenol (HL-Bn) or its 2,6-dichlorobenzyl analogue (HL-BnCl2) with Fe(H2O)6(ClO4)2 in the presen

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::54b4aae213b196eecce215fd5fdea6b5
https://hal.archives-ouvertes.fr/hal-00169629