Zobrazeno 1 - 10
of 97
pro vyhledávání: '"BRIAN G. GOWENLOCK"'
PES bands due to ionization from n*, n and π orbitals of the NO group in some aliphatic nitroso compounds have been identified. In nitrosobenzene derivatives only the n*(NO) band can be assigned unequivocally. Substituent effects on the ionization e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::178eeaf20877484aad7b36d5fd1187eb
https://ora.ox.ac.uk/objects/uuid:931ca67d-bb4f-4460-bef5-4f07fd6269cb
https://ora.ox.ac.uk/objects/uuid:931ca67d-bb4f-4460-bef5-4f07fd6269cb
Publikováno v:
Tradition and Discovery: The Polanyi Society Periodical. 34:31-43
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2061a9582408a390d192b68995993f2d
https://doi.org/10.5840/traddisc2007/200834348
https://doi.org/10.5840/traddisc2007/200834348
Autor:
Brian G. Gowenlock, Thomas R. Sharpe
Publikováno v:
Synthesis. 2006:1991-1994
The reaction of nitrosyl benzoate with tetrasubstituted alkenes at 0 °C produces monomeric C-nitroso compounds in high yields. Similarly, the reaction of dinitrosyl terephthalate with 2,3-dimethylbut-2-ene affords a monomeric dinitroso compound. Ext
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4056030577bd3dbdc0429e21b5dcc560
https://doi.org/10.1055/s-2006-942392
https://doi.org/10.1055/s-2006-942392
Publikováno v:
Chemical Reviews. 104:3315-3340
The discovery of important roles of C-nitroso compounds in various biological metabolic processes has generated a renewed interest in the general chemical properties of nitrosoalkanes (R–N=O; R =alkyl) and nitrosoarenes (ArNO; Ar =aryl), two import
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a9c3467bfbda8962336299c496e4a54
https://doi.org/10.1021/cr030450k
https://doi.org/10.1021/cr030450k
Autor:
John C. Bevington, Brian G. Gowenlock
Publikováno v:
Biographical Memoirs of Fellows of the Royal Society. 48:289-308
Sir Harry Melville was a physical chemist with an international reputation for his studies of gas-phase and heterogeneous reactions, polymerizations and polymer properties; much of this work was characterized by the development of analytical techniqu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5e4a11ca0179f392279e6f5f655a7ff6
https://doi.org/10.1098/rsbm.2002.0016
https://doi.org/10.1098/rsbm.2002.0016
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1904-1911
A series of mono- and di-methyl substituted p-nitrosoanisoles was synthesised either by direct nitrosation of the anisoles with NO+HSO4− or by mild oxidation (H2O2–Mo catalyst) of the appropriate amines. The nature of these compounds in solution
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c824bf467d2e706a28507b105fa64730
https://doi.org/10.1039/b105955f
https://doi.org/10.1039/b105955f
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 105:353-355
The 13C NMR spectra of a wide range of monomeric para-substituted nitrosobenzenes have been determined and the results related to a wide range of published data for other para-disubstituted benzenes. It is shown that the nitroso substituent exercises
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e081d96521e123d24c1e355e8b0f8837
https://doi.org/10.1002/recl.19861051004
https://doi.org/10.1002/recl.19861051004
Autor:
Giuseppe Mele, Mark J. Maidment, Michael B. Hursthouse, Keith G. Orrell, Vladimir Šik, K.M. Abdul Malik, Brian G. Gowenlock, Giuseppe Vasapollo
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :2280-2286
2-Nitrosopyridine, 1, 3-methyl-2-nitrosopyridine, 2, and 4-methyl-2-nitrosopyridine, 3, exist in organic solvents as monomer–azodioxy dimer equilibria with the dimers predominating at ambient temperatures. In the case of compounds 1 and 3 only the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::905bc68c1c770e6c35eb5a4052d1a020
https://doi.org/10.1039/b004270f
https://doi.org/10.1039/b004270f
Publikováno v:
Polyhedron. 17:3495-3500
σ N -Coordinated compounds [PtCl 3 (4-X-C 6 H 4 NO)] - K + have been prepared and studied by 13 C NMR spectroscopy and by variable temperature 1 H NMR spectroscopy. It is shown that the anomalous behaviour of the NO group on the 13 C chemical shifts
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::239a77f49c03e22f228c706f0f9159a7
https://doi.org/10.1016/s0277-5387(98)00137-5
https://doi.org/10.1016/s0277-5387(98)00137-5
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :797-804
Energy barriers associated with rotation of nitroso groups in monomeric nitrosobenzene and eleven monomeric substituted nitrosobenzenes in solution have been measured by total 1H NMR bandshape analysis. ΔG ‡ (298.15 K) values for the rotations are
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7698f97cabe367a45a850da5865ac9af
https://doi.org/10.1039/a708653i
https://doi.org/10.1039/a708653i