Zobrazeno 1 - 10
of 51
pro vyhledávání: '"BENJAMIN F. PLUMMER"'
Autor:
Angelika Niemz, L. Kraig Steffen, and Benjamin F. Plummer, Alejandro O. Cuello, Vincent M. Rotello
Publikováno v:
Journal of the American Chemical Society. 122:4798-4802
We have explored the effect of resonance overlap on electronic communication in σ-bonded π-systems through a combined experimental and computational investigation. The system studied consists of a series of diphenyl-substituted acenaphthofluoranthe
Autor:
Marilyn Wooten, Saadia Faiz, William H. Watson, Mitchell D. Miller, Ted Wiederhold, Joseph K. Agyin, Kurt L. Krause, Benjamin F. Plummer
Publikováno v:
The Journal of Organic Chemistry. 62:9290-9294
The Diels−Alder (D−A) reaction of the twisted hydrocarbon 1,4-diphenylbenz[a]aceanthrylene (4) with dienophiles maleic anhydride, bromomaleic anhydride, and N-phenylmaleimide and with benzyne is reported. The stereochemistry of the products deriv
Autor:
Benjamin F. Plummer, Michael Gill, Tala L. Braley, W. Greg Reese, Kathryn Zych, L. Kraig Steffen, Gregory Van Dyke
Publikováno v:
Journal of Physical Organic Chemistry. 10:623-630
The oxidation and reduction potentials of a series of related even non-alternant derivatives of 7,14-disubstituted acenaphth[1,2-k] fluoranthenes, and also fluoranthene, 7,10-diphenylfluoranthene and 8,9-dihydrodiindeno[1,2-j;2′,1′-] fluoranthene
Autor:
Stephen J. Russell, Benjamin F. Plummer, Susan A. Bourne, William H. Watson, Jo Ann Currey, L. K. Steffen
Publikováno v:
Structural Chemistry. 6:167-173
The reaction of 4,5-didehydroacenaphthene with phencyclone yields the title compound, a stable dibenzo-fused norbornadienone (8). The X-ray structure of8 is presented and compared with the structure predicted from a MM3, PM3, and a MMX calculation. T
Publikováno v:
The Journal of Physical Chemistry. 98:7470-7474
Autor:
Benjamin F. Plummer
Publikováno v:
Polycyclic Aromatic Compounds. 4:25-39
The utility of molecular modeling in interpreting the 1H NMR spectra of selected polycyclic aromatic hydrocarbons that are deformed from their normal geometries is illustrated. The application of COSY and NOESY 1H NMR spectra in conjunction with the
Autor:
Tala L. Braley, L. Kraig Steffen, Gregory Van Dyke, Benjamin F. Plummer, W. Greg Reese, Brock Tulley, Kathryn Zych
Publikováno v:
Journal of the American Chemical Society. 115:11542-11551
A detailed study of the electronic behavior of a series of even nonalternant polycyclic aromatic hydrocarbons derived from fluoranthene is presented. Compounds were synthesized that contained substantial barriers to rotation of substituents into conj
Publikováno v:
Structural Chemistry. 4:279-285
Several of the readily available theoretical programs are evaluated as tools for modeling the structures of polycyclic aromatic hydrocarbons with five-membered rings (CPAHs). The experimentally determined bond lengths and angles are compared to calcu
Autor:
Benjamin F. Plummer
Publikováno v:
Polycyclic Aromatic Compounds. 3:77-88
This review focuses on physico-chemical aspects of cyclopentene-fused polycyclic aromatic hydrocarbons (CPAH) that we are currently studying. Steric effects, deformation of polycyclic skeletons from planarity, radical ions, and excited states are pro
Publikováno v:
ChemInform. 22
C 17 H 6 Cl 6 cristallise dans P2 1 /c avec a=14,814, b=8,623, c=14,206 A, β=111,22°, Z=4; affinement jusqu'a R=0,0488. Cette molecule est constituee d'un systeme naphtalene joint a une molecule d'hexachloronorbornadiene, et est plane. Les atomes C