Zobrazeno 1 - 10
of 35
pro vyhledávání: '"B.H. Sakakini"'
Publikováno v:
Journal of Catalysis. 235:103-113
The role of Cs and Cl in promoting selectivity in ethene epoxidation over a Ag/α-Al2O3 catalyst was examined by determining their effect, singly and in combination, on the kinetics of adsorption and desorption of oxygen on that catalyst. Cs has been
The activity and selectivity of oxygen atoms adsorbed on a Ag/?-Al2O3 catalyst in ethene epoxidation
Publikováno v:
Catalysis Letters. 99:45-53
The bonding of the oxygen species held on a Ag/α-Al2O3 catalyst has been studied by temperature programmed desorption and their reactivity in ethene epoxidation by temperature programmed reduction using ethene as the reductant. The Ag/α-Al2O3 catal
Publikováno v:
Journal of Catalysis. 221:313-318
A method which we have termed “dynamic infrared spectroscopy” that allows the determination of the value of the desorption rate constant of a specified adsorbate by monitoring the decay with time of the intensity of a given infrared band at a fix
Publikováno v:
Catalysis Letters. 82:261-270
The partial oxidation of CH3OH to CO2 and H2 over a Cu/ZnO/Al2O3 catalyst has been studied by temperature-programmed oxidation (TPO) using N2O and O2 as the oxidant. Post-reaction analysis of the adsorbate composition of the surface of the catalyst w
Publikováno v:
Journal of Catalysis. 189:253-262
The interaction of n-butane with a ((VO)2P2O7) catalyst has been investigated by temperature-programmed desorption and anaerobic temperature-programmed reaction. n-Butane has been shown to adsorb on the (VO)2P2O7 to as a butyl–hydroxyl pair. When a
Publikováno v:
Catalysis Letters. 59:151-155
The coverage-dependent sticking probabilities of molecular hydrogen on polycrystalline copper supported on alumina have been determined in the temperature range 213–273 K by analysis of the hydrogen frontal adsorption line shape. In this temperatur
Publikováno v:
Catalysis Letters. 59:143-149
The kinetics of desorption of hydrogen from the copper component of an alumina-supported polycrystalline copper catalyst has been studied in detail by temperature-programmed desorption (TPD). Line-shape analysis of the hydrogen TPD spectra shows: (i)
Publikováno v:
Journal of Catalysis. 167:164-171
Ceramic model catalysts of general formula Bi4V2−xSbxO11−δare synthesised by solid-state reaction. X-ray diffraction shows the materials to be single phase over the composition range 0 ≤ x < 0.3, with a second phase, which is not identified, p
Publikováno v:
Catalysis Letters. 46:273-277
The mechanism of the selective partial oxidation of n-butane, but-1-ene and but-1,3-diene over a vanadyl phosphate catalyst has been investigated by temperature-programmed desorption (TPD) and by anaerobic temperature-programmed oxidation (TPO). TPD
Publikováno v:
Catalysis Letters. 48:105-110
The anaerobic oxidation of CO by a (VO)2P2O7 catalyst has been used to investigate the nature of the oxidant (selective and unselective) in/on that material. Three peaks were observed in the rate of production of CO2 - at 993, 1073 and 1093 K. The te