Zobrazeno 1 - 10
of 10
pro vyhledávání: '"B. T. Carvill"'
Publikováno v:
The Journal of Physical Chemistry B. 102:1750-1758
EXAFS and XRD, the latter in the advanced mode of Debye function analysis (DFA), were combined to investigate the effect of preparation conditions on the size of Pd clusters inside the cavities of zeolite Y. It is concluded that the macroscopic size
Publikováno v:
Catalysis Today. 21:23-35
Exposure to water vapor of calcined precursors of 0.5% Pt/H- Mordenite catalysts before reduction induces formation of larger Pt particles after reduction, but also enhances the catalytic activity for methylcyclopentane (MCP) conversion. Adsorption o
Publikováno v:
Journal of Catalysis. 144:1-8
The conversion of n-heptane was studied on Pt/HMor. The response of catalytic activity and isomerization selectivity to reduction temperature and metal dispersion is contrary to that known for Pt on amorphous supports or on zeolites with three-dimens
Publikováno v:
Journal of Catalysis. 143:314-317
Publikováno v:
Catalysis Letters. 18:227-234
The distribution of methylcyclopentane (MCP) ring enlargement (RE) products between benzene (Bz) and cyclohexane (CH) provides information on the reaction mechanism. The Bz/CH ratio is in excess of the calculated and experimentally determined equilib
Publikováno v:
ChemInform. 26
Exposure to water vapor of calcined precursors of 0.5% Pt/H- Mordenite catalysts before reduction induces formation of larger Pt particles after reduction, but also enhances the catalytic activity for methylcyclopentane (MCP) conversion. Adsorption o
Publikováno v:
Journal of Molecular Catalysis. 77:99-108
Preparations of Pt/mordenite and Pt/Y catalysts varying in metal load and proton concentration have been studied. Temperature-programmed reduction (TPR) and temperature-programmed desorption (TPD) have been used to characterize the metal species. Hig
Publikováno v:
Applied Organometallic Chemistry. 6:463-478
Sulfide cluster-derived ensembles are promising models of the active sites in commercial hydrotreatment catalysts. A series of sulfide clusters were adsorbed intact onto high-surface-area γ-alumina, magnesium oxide and activated carbon supports, the
Autor:
Levi T. Thompson, B. T. Carvill
Publikováno v:
Applied Catalysis. 75:249-265
There is growing interest in the use of organometallic clusters as precursors to model heterogeneous catalysts. This interest is partially derived from the expectation that “solid-state metal complex catalysts” will be uniform in composition and
Publikováno v:
Journal of the Chemical Society, Faraday Transactions. 90:233
The state and dispersion of Pt supported on mordenite have been studied using FTIR spectroscopy, CO Chemisorption, and H–D isotope exchange of cyclopentane. Under conditions for which other criteria indicate the presence of monatomic Pt0, a charact