Zobrazeno 1 - 10
of 73
pro vyhledávání: '"B. S. Thyagarajan"'
Publikováno v:
ChemInform. 22
Reaction of sodium benzenesulfinate with 1,2-di(4-chloro-benzenesulfonyl)-2-hexen-4-yne affords not only the regiospecific addition of the nucleophile at Carbon-5 but also effects concomitant vinylic and allylic displacements at Carbons-1 and 2
Publikováno v:
ChemInform. 22
Reaction of sodium benzenesulphinate with 1,2-di(4-chlorobenzenesulphonyl)hex-2-en-4-yne affords not only the regiospecific addition of the nucleophile at C(5) but also effects concomitant vinylic and allylic displacements at C(1) and (2).
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 57:17-23
Reaction of sodium benzenesulfinate with 1,2-di(4-chloro-benzenesulfonyl)-2-hexen-4-yne affords not only the regiospecific addition of the nucleophile at Carbon-5 but also effects concomitant vinylic and allylic displacements at Carbons-1 and 2
Autor:
B. S. Thyagarajan, R. A. Chandler
Publikováno v:
ChemInform. 21
The hexa-2,4-diene derivative (2), obtained from 1,6-di(phenylsulphonyl)hexa-2,4-diyne (1), is shown to undergo simultaneous Isomerization at both double bonds, through an elimination-addition pathway.
Autor:
B. S. Thyagarajan
Publikováno v:
Journal of Chemical Education. 73:A110
Principles of Medicinal Chemistry is an eminently readable textbook for beginning students of medicinal chemistry. It is not exhaustive, but it is "comprehensive enough to help students pass their courses in medicinal chemistry".
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1464
Reaction of sodium benzenesulphinate with 1,2-di(4-chlorobenzenesulphonyl)hex-2-en-4-yne affords not only the regiospecific addition of the nucleophile at C(5) but also effects concomitant vinylic and allylic displacements at C(1) and (2).
Autor:
R. A. Chandler, B. S. Thyagarajan
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :328
The hexa-2,4-diene derivative (2), obtained from 1,6-di(phenylsulphonyl)hexa-2,4-diyne (1), is shown to undergo simultaneous Isomerization at both double bonds, through an elimination-addition pathway.
Autor:
B. S. Thyagarajan, K. C. Majumdar
Publikováno v:
Journal of Heterocyclic Chemistry. 11:937-942
The condensations of urethanes with formaldehyde under appropriate experimental conditions affords either 1,3,5-triazines or 1,3,5,7-tetrazoeines. The two systems are interconvertible under acid catalysis.
Publikováno v:
Phosphorus and Sulfur and the Related Elements. 21:357-366
Base-catalyzed addition of arene thiols to 1,4-disubstituted-2-butynes (1 and 2) afford the β,γ-unsaturated sulfones (8E and 8Z). In addition to the regiospecificity observed, the vinyl sulfides are formed with a high degree of stereoselectivity. P
Publikováno v:
Phosphorous and Sulfur and the Related Elements. 26:275-284
Regioselectivity is restored in the addition of thiols to 1,4-diarylsulfonyl-2-butynes based on differing electron-demands of the substituents on the aromatic rings attached to the butynyl sulfones. Kinetic control of addition leading to preponderant