Zobrazeno 1 - 10
of 21
pro vyhledávání: '"B. S. Gudkov"'
Publikováno v:
Russian Chemical Bulletin. 49:1373-1379
Temperature hysteresis is observed only in exothermic heterogeneous catalytic reactions (viz., oxidation and methanation of CO or propene hydrogenation) and is absent in the case of endothermic reactions (dehydrogenation of isobutane) or reactions wi
Publikováno v:
Reaction Kinetics and Catalysis Letters. 66:97-104
The temperature hysteresis observed in the oxidation of CO on both supported and unsupported catalysts can be explained by the local overheating of active centers rather than by transitions from one steady state to another.
Publikováno v:
Russian Journal of Applied Chemistry. 75:582-584
The temperature hysteresis during the heterogeneous catalysis was studied by an example of model reaction of CO oxidation on copper oxide catalyst applied to a stainless steel gauze.
Autor:
B. S. Gudkov, E. Z. Golosman, A. N. Subbotin, S. V. Chertkova, V. I. Yakerson, G. V. Kozyreva
Publikováno v:
Russian Journal of Applied Chemistry. 74:1506-1508
The temperature dependence of the degree of CO oxidation with atmospheric oxygen on coppercement catalysts was studied.
Autor:
V. I. Yakerson, Z. T. Beisembaeva, N. V. Nekrasov, Z. A. Ibraeva, B. S. Gudkov, E. Z. Golosman, S. L. Kiperman
Publikováno v:
Theoretical and Experimental Chemistry. 26:584-588
The kinetics of hydrogenation of CO2 to methane on an NKM-4A nickel-containing catalyst was studied in a wide range of change of partial pressures of hydrogen and carbon dioxide at 498–543 K. It was shown that when hydrogen is replaced by deuterium
Publikováno v:
Web of Science
It has been demonstrated that metallic copper of various (but not any) genesis can dissociatively adsorb hydrogen and that atomic hydrogen takes part in the hydrogenation of n - and isobutyric aldehydes on copper-containing catalysts.
Publikováno v:
Collection of Czechoslovak Chemical Communications. 49:2400-2409
The reaction of thiophene with deuterium on aluminia supported Ni-, Mo- and Ni-Mo-catalysts (laboratory samples) and Ni-W-, Ni-Mo- and Co-Mo-catalysts (commercial samples) was investigated at 150-455°C and different D2/C4H4S ratio in a closed system
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:481-485
1. The isomeric composition of isoamylenes formed during hydrogenation of isoprene on a Pd-Pb catalyst is not significantly dependent on the conditions of the reaction and differs from the equilibrium composition. The rate of formation of each isomer
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:681-687
1. Data were obtained on the rates of hydrogenation and isotopic exchange with deuterium of benzene and its alkyl derivatives, permitting a comparison of the basic principles of these processes. 2. In the transition from one hydrocarbon to another, t
Autor:
László Guczi, B. S. Gudkov
Publikováno v:
Reaction Kinetics and Catalysis Letters. 9:343-347
The effect of the dispersity of a Pt/SiO2 catalyst has been investigated in the hydrogenolysis of ethane, n-butane and in cyclohexane exchange. Turnover number, NT, for ethane hydrogenolysis increases with decreasing particle size, which may be inter