Zobrazeno 1 - 10
of 49
pro vyhledávání: '"B. P. Bering"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:1817-1822
1. The thermal equations of adsorption were derived for the region of temperatures above and below the critical temperature (adsorption of gas and vapor) for the linear isotherms of adsorption, permitting a calculation of the isotherms and isosteres
Autor:
V. V. Serpinskii, B. P. Bering
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:2610-2615
1. A thermodynamic method of determining the capacity of a monomolecular layer and, consequently, the specific surface for nonporous adsorbents, based on an analysis of the adsorption isotherms of vapors at different temperatures and a calculation of
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2258-2261
Dilatometer and adsorption measurements have established that there is a direct proportionality between the change in free energy of the vacancy solution and the relative alteration of the dimensions of the X type calcium and lanthanum ion exchange z
Autor:
B. P. Bering, V. V. Serpinskii
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:2616-2621
1. The concept of “adsorption vacancies” as elements of the adsorption volume, filled by adsorbed molecules, was introduced. Adsorption on a solid from a homogeneous gas phase is considered as a process of formation of a binary solution of molecu
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:1813-1816
1. The thermodynamics of adsorption was considered for the case when the equilibrium gas phase is sharply nonideal, and it was shown, in particular, that in this region it is advisable to use not the values of the heats of adsorption, but the values
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2606-2609
1. The initial heat of krypton adsorption on zeolite NaX is 15.3 kJ/mole. 2. The partial molar enthalpy of the adsorbate under isosteric conditions increases with increase in the temperature. 3. The partial molar isosteric heat capacity of the adsorb
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:659-666
Autor:
V. V. Serpinskii, B. P. Bering
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:2342-2353
1. A new thermodynamic theory of adsorption equilibrium was proposed, based on the application of the thermodynamics of solutions to a universal model of a vacancy solution, corresponding to equilibrium of the gas phase with a solid. 2. The applicati
Autor:
B. P. Bering, V. V. Serpinskii
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1513-1519
1. The osmotic theory of adsorption equilibrium has been extended by deriving and experimentally testing a thermodynamically exact, five-parameter, thermal-adsorption equation. This equation gives a good description of zeolite adsorption of xenon and
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:419-422
1. Conditions were found where the experimental adsorption isotherms are simultaneously described by the equations of the theory of the bulk filling of micropores and the osmotic adsorption theory. 2. The relationships between the parameters of these