Zobrazeno 1 - 10
of 42
pro vyhledávání: '"B. L. Erussalimsky"'
Publikováno v:
Macromolecular Symposia. 128:221-230
Experimental conditions ensuring the formation of living poly(2- and 4-vinyl pyridine) chains in the vinyl pyridine - allyl derivatives of chromium, molybdenum and tungsten systems are described. Variation of the reagents nature, polarity of the solv
Publikováno v:
Macromolecular Chemistry and Physics. 196:1017-1021
The probability of interaction of anionically growing poly(acrylonitrile) chains with DMF in the acrylonitrile (AN)-RLi-DMF system was investigated by means of NMR and semiempirical, quantum chemical calculations (MNDO). According to the NMR data, po
Publikováno v:
Scopus-Elsevier
In contrast to the data related to the BuLi-vinyl pyridine systems, 4-vinyl pyridine is distinguished by much greater activity as compared with 2-vinyl pyridine in the polymerization induced by tris-π-allyl chronium. The experimental results illustr
Publikováno v:
Macromolecular Theory and Simulations. 3:633-637
The energetic and electronic parameters of various mono- and bidentate complexes of CH3Li with N- and O-containing electron donors were calculated by the MNDO method. It was shown that N,N,N′,N′-tetramethylethylenediamine (TMD) forms a more stabl
Publikováno v:
Macromolecular Theory and Simulations. 3:489-495
Taking as examples cyclic halonium (I) and linear carbenium (II) model cations of equal composition, viz. [Cl(CH 2 ) 4 ] + , and products of propene addition to them (V and VI), the energetic characteristics of these structures were estimated by the
Publikováno v:
Journal of Macromolecular Science, Part A. 31:261-272
Semiempirical MNDO calculations of model systems simulating cationic initiating systems of the BCI3/ester type have been carried out. Interactions between BX3 (X = F, CI) and methyl acetate (MA) have been compared. Properties of six-membered cyclic t
Publikováno v:
Die Makromolekulare Chemie, Theory and Simulations. 2:805-813
With the aim to find the causes of the different stereochemical behavior characteristic of the anionic acrylonitrile (AN) and methyl acrylate (MA) growing chains, the following model systems were investigated using the MNDO1 (method: 1) compounds XCH
Publikováno v:
Die Makromolekulare Chemie, Theory and Simulations. 1:261-271
The electronic and geometric structures of the CH3Li/acrylonitrile (AN) and CH3Li/2AN systems were investigated by the semiempirical quantum-chemical MNDO1 method. For the CH3Li/AN system a fundamental difference was found between the predictions of
Synthese und charakterisierung der in anionischen systemen hergestellten polaren hybridmakromoleküle
Publikováno v:
Acta Polymerica. 43:38-46
Pfropf- und Copolymere aus polaren Monomeren werden hinsichtlich ihrer Synthese und Charakterisierung naher beschrieben. Im Falle der Pfropfcopolymere sind aktivierte P2VP-, P4VP, PVAC- und PMMA-Ketten die Voraussetzung fur die Monomeraddition. Dabei
Autor:
B. L. Erussalimsky, I. A. Baranovskaya, V. D. Krasikov, I.G. Krasnosel'skaya, L. V. Vinogradova, Stanislav I. Klenin
Publikováno v:
Journal of Macromolecular Science: Part A - Chemistry. 28:121-128
The polymerization in the system acrylonitrile (AN) - tributyl dimagnesium iodide (TUI) - toluene in the presence of small amounts of 2-vinylpyridine (VP) begins with the formation of short living oligo-blocks of VP which induce the polymerization of