Zobrazeno 1 - 10
of 31
pro vyhledávání: '"B. K. Seal"'
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :531-534
Formation constants of 1∶1 adducts of [60]fullerene with naphthalene, phenanthrene, anthracene, pyrene and chrysene have been determined in CCl4 medium. Ionisation potentials of donor molecules and charge transfer (CT) transition energies of the [6
Autor:
Manas Banerjee, Tridibranjan Roy, Kakali Datta, B. K. Seal, Mrinal K. Nayek, Asok K. Mukherjee
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :2219-2223
The well-known electron acceptor, p-chloranil (A) and donor, N,N′-diphenylthiourea (B) have been observed to form a labile charge-transfer (CT) complex (AB), which decays slowly into two products viz. 2,3,5-trichloro-6-(N,N′-diphenylthioureido)be
Publikováno v:
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 53:2587-2594
The electron donor–acceptor (EDA) interactions between o -chloranil and a series of phenols have been studied in dioxan medium. Except for resorcinol, the EDA complexes are formed instantaneously on mixing the donor and the acceptor solutions and t
Autor:
Dipak K. Chatterjee, B. K. Seal
Publikováno v:
Proceedings / Indian Academy of Sciences. 104:409-416
ViscosityB-coefficients of sodium salts of salicylic, thiosalicylic, anthranilic, 2,6-dihydroxy benzoic and ito-anisic acids have been measured at 298, 303 and 308 K respectively. Temperature dependence ofB-values suggest that the salts as well as th
Publikováno v:
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 57(2)
The equilibrium constants, enthalpies and entropies of formation of molecular electron donor-acceptor (EDA) complexes of o-chloranil with a series of aromatic hydrocarbons have been determined spectrophotometrically. Spectroscopic and thermodynamic a
Autor:
M. W. Kuchenbecker, E. Y. Kwok, Jacques R. Tabanou, S. D. Bonner, J. P. Seydoux, K. A. Moriarty, Peter T. Wu, B. K. Seal
Publikováno v:
All Days.
Abstract To address the increasing number of slim holes being drilled in the range of 5.75 in. to 6.75 in., a mixed-borehole- compensated (MBHC) 2-MHz array resistivity tool with a 4.75-in. collar diameter is described for resistivity cement-while-dr
Autor:
B. K. Seal, Mahadeb Roy
Publikováno v:
Proceedings / Indian Academy of Sciences. 106
From solvatochromicity of CT-band maxima of complexes of TCNE with methylbenzenes in several apolar and polar solvents the inductive effect parameter,h Me, of the methyl group has been calculated by the Coulson-Longuet-Higgins perturbation theory. Fr
Publikováno v:
Spectrochimica Acta Part A: Molecular Spectroscopy. 38:289-292
The Benesi—Hildebrand equation and its modified forms have been rearranged to give equations which enable independent evaluation of K and ϵ of molecular complexes from spectrophotometric data by graphical procedure. The equations have been tested
Publikováno v:
Journal of Magnetic Resonance (1969). 51:318-322
which is the NMR analog of the well-known Benesi and Hildebrand (2) equation used for the determination of association constants and molar absorptivities of CT complexes from optical spectrophotometric data. The observed chemical shift is A, c”o re
Publikováno v:
Bulletin of the Chemical Society of Japan. 55:1620-1623
Job’s method of continuous variation has been reinvestigated with respect to the formation of 1 : 1 type complex from the view point of (i) geometrical significance of the Job curve, (ii) developing a method for determining the equilibrium constant